Hollow and filled rectangular parallelopiped carbon nanocapsules catalyzed by calcium and strontium

被引：4
作者：
Saito, Y [1 ]
Matsumoto, T [1 ]
机构：
[1] Mie Univ, Dept Elect & Elect Engn, Tsu, Mie 514, Japan
来源：
JOURNAL OF CRYSTAL GROWTH | 1998年 / 187卷 / 3-4期
关键词：
nanoparticle; carbon nanocapsule; graphite; calcium; strontium;
D O I：
10.1016/S0022-0248(98)00013-X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new form of graphitic cages in nanometer scale, rectangular parallelopiped (or cube), was produced by are evaporation of a carbon electrode containing calcium or strontium. Both the empty and the filled rectangular nanocapsules averaging 20-100 nm in size were formed, though the empty ones were dominant. The rectangular cages were made up of multi-walled (5-20 layers) graphitic carbon. The encapsulated materials were beta-CaC2(tetragonal), gamma-CaC2(cubic) and delta-CaC2 (monoclinic) for C/Ca evaporation, and beta-SrC2 (tetragonal) and metallic Sr for C/S revaporation. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：402 / 409
页数：8
相关论文
共 26 条
  • [1] ATOMS IN CARBON CAGES - THE STRUCTURE AND PROPERTIES OF ENDOHEDRAL FULLERENES
    BETHUNE, DS
    JOHNSON, RD
    SALEM, JR
    DEVRIES, MS
    YANNONI, CS
    [J]. NATURE, 1993, 366 (6451) : 123 - 128
  • [2] The polymorphism of calcium carbide
    Bredig, MA
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1942, 46 (07) : 801 - 819
  • [3] MAGNETIC-PROPERTIES OF CARBON-COATED, FERROMAGNETIC NANOPARTICLES PRODUCED BY A CARBON-ARC METHOD
    BRUNSMAN, EM
    SUTTON, R
    BORTZ, E
    KIRKPATRICK, S
    MIDELFORT, K
    WILLIAMS, J
    SMITH, P
    MCHENRY, ME
    MAJETICH, SA
    ARTMAN, JO
    DEGRAEF, M
    STALEY, SW
    [J]. JOURNAL OF APPLIED PHYSICS, 1994, 75 (10) : 5882 - 5884
  • [4] FULLERENES WITH METALS INSIDE
    CHAI, Y
    GUO, T
    JIN, CM
    HAUFLER, RE
    CHIBANTE, LPF
    FURE, J
    WANG, LH
    ALFORD, JM
    SMALLEY, RE
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (20) : 7564 - 7568
  • [5] CONTROLLED-SIZE NANOCAPSULES
    DRAVID, VP
    HOST, JJ
    TENG, MH
    ELLIOT, B
    HWANG, JH
    JOHNSON, DL
    MASON, TO
    WEERTMAN, JR
    [J]. NATURE, 1995, 374 (6523) : 602 - 602
  • [6] MAGNETIC-PROPERTIES OF IRON IN NANOCAPSULES
    HIHARA, T
    ONODERA, H
    SUMIYAMA, K
    SUZUKI, K
    KASUYA, A
    NISHINA, Y
    SAITO, Y
    YOSHIKAWA, T
    OKUDA, M
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1994, 33 (1A): : L24 - L25
  • [7] PENTAGONS, HEPTAGONS AND NEGATIVE CURVATURE IN GRAPHITE MICROTUBULE GROWTH
    IIJIMA, S
    ICHIHASHI, T
    ANDO, Y
    [J]. NATURE, 1992, 356 (6372) : 776 - 778
  • [8] HELICAL MICROTUBULES OF GRAPHITIC CARBON
    IIJIMA, S
    [J]. NATURE, 1991, 354 (6348) : 56 - 58
  • [9] Structures of the Ca@C-82 isomers: A theoretical prediction
    Kobayashi, K
    Nagase, S
    [J]. CHEMICAL PHYSICS LETTERS, 1997, 274 (1-3) : 226 - 230
  • [10] C-60 - BUCKMINSTERFULLERENE
    KROTO, HW
    HEATH, JR
    OBRIEN, SC
    CURL, RF
    SMALLEY, RE
    [J]. NATURE, 1985, 318 (6042) : 162 - 163
123