Synthesis and Catalytic Performance of Na2HfM(PO4)3 and Ag2-xNaxHfM(PO4)3 (M = Fe and Al and 0.07 ≤ x ≤ 0.13)

被引：1

作者：

Palla, Suresh ^{[1
]}

Veldurthi, Naveen Kumar ^{[1
]}

Guje, Ravinder ^{[1
]}

Prasad, G. ^{[2
]}

Munirathnam, N. R. ^{[3
]}

Vithal, M. ^{[1
]}

机构：

[1] Osmania Univ, Dept Chem, Hyderabad 500007, Andhra Pradesh, India

[2] Osmania Univ, Dept Phys, Hyderabad 500007, Andhra Pradesh, India

[3] IDA, Ctr Mat Elect Technol, Hyderabad, Andhra Pradesh, India

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2015年 / 45卷 / 05期

关键词：

sol gel synthesis; photocatalysis; CONDUCTIVITY; DISORDER; SPECTRA; CR;

D O I：

10.1080/15533174.2013.843546

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Materials belonging to NASICON family of compositions Na2HfM(PO4)(3) and Ag2-xNaxHfM(PO4)(3) (M = Fe and Al and 0.07 <= x <= 0.13) are prepared by sol-gel and ion exchange methods, respectively. The IR spectra are characterized by bands belonging to PO4 groups. The band gap energy of all compositions is obtained from their UV-vis DRS profiles. All these materials are used as catalysts in the degradation of methylene blue and methyl orange under visible light irradiation. The silver compounds have shown good catalytic activity compared to their sodium analogues. The catalysts are stable even after the third cycle of photodegradation.

引用

页码：730 / 739

页数：10

共 33 条

[1] STRUCTURE AND THERMAL-EXPANSION OF LIGE2 (PO4)3 [J].

ALAMI, M ;

BROCHU, R ;

SOUBEYROUX, JL ;

GRAVEREAU, P ;

LEFLEM, G ;

HAGENMULLER, P .

JOURNAL OF SOLID STATE CHEMISTRY, 1991, 90 (02) :185-193

[2] FT-IR and FT-Raman study of Nasicon type phosphates, ASnFe(PO4)3 [A = Na2, Ca, Cd] [J].

Antony, C. J. ;

Aatiq, A. ;

Panicker, C. Yohannan ;

Bushiri, M. Junaid ;

Varghese, Hema Tresa ;

Manojkumar, T. K. .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2011, 78 (01) :415-419

[3] Silver-cluster formation on AgZr2(PO4)(3) and catalytic decomposition of butan-2-ol [J].

Arsalane, S ;

Ziyad, M ;

Coudurier, G ;

Vedrine, JC .

JOURNAL OF CATALYSIS, 1996, 159 (01) :162-169

[4] AgNaMordenite catalysts for hydrocarbon adsorption and deNOx processes [J].

Aspromonte, Soledad G. ;

Serra, Ramiro M. ;

Miro, Eduardo E. ;

Boix, Alicia V. .

APPLIED CATALYSIS A-GENERAL, 2011, 407 (1-2) :134-144

[5]

Barhon Z., 2012, Journalof Materials and Environmental Science, V3, P879

[6] RAMAN AND INFRARED-SPECTRA OF SOME CHROMIUM NASICON-TYPE MATERIALS - SHORT-RANGE DISORDER CHARACTERIZATION [J].

BARJ, M ;

LUCAZEAU, G ;

DELMAS, C .

JOURNAL OF SOLID STATE CHEMISTRY, 1992, 100 (01) :141-150

[7] RELATIONS BETWEEN SUBLATTICE DISORDER, PHASE-TRANSITIONS AND CONDUCTIVITY IN NASICON [J].

BARJ, M ;

PERTHUIS, H ;

COLOMBAN, P .

SOLID STATE IONICS, 1983, 9-10 (DEC) :845-850

[8] EXISTENCE DOMAINS, STRUCTURAL DISTORTIONS AND VIBRATION MODES OF CONDUCTING IONS IN NASICON TYPE HOST LATTICES [J].

BARJ, M ;

PERTHUIS, H ;

COLOMBAN, P .

SOLID STATE IONICS, 1983, 11 (02) :157-177

[9] Particular characteristics of silver species on Ag-exchanged LTL zeolite in K and H form [J].

Bartolomeu, Rui ;

Bertolo, Raquel ;

Casale, Sandra ;

Fernandes, Auguste ;

Henriques, Carlos ;

da Costa, Patrick ;

Ribeiro, Filipa .

MICROPOROUS AND MESOPOROUS MATERIALS, 2013, 169 :137-147

[10] Characterization of active sites on AgHf2(PO4)3 in butan-2-ol conversion [J].

Brik, Y ;

Kacimi, M ;

Bozon-Verduraz, F ;

Ziyad, M .

MICROPOROUS AND MESOPOROUS MATERIALS, 2001, 43 (01) :103-112

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