The Photocatalytic Performance of Nd2O3 Doped CuO Nanoparticles with Enhanced Methylene Blue Degradation: Synthesis, Characterization and Comparative Study

被引:21
作者
El-Sayed, Fatma [1 ]
Hussien, Mai S. A. [1 ,2 ]
Mohammed, Mervat, I [1 ]
Ganesh, Vanga [3 ]
AlAbdulaal, Thekrayat H. [3 ]
Zahran, Heba Y. [3 ,4 ,5 ]
Yahia, Ibrahim S. [3 ,4 ,5 ]
Hegazy, Hosam H. [3 ,6 ]
Abdel-wahab, Mohamed Sh [7 ]
Shkir, Mohd [3 ]
Valarasu, Santiyagu [8 ]
Ibrahim, Medhat A. [9 ,10 ]
机构
[1] Ain Shams Univ, Fac Educ, Dept Phys, Nanosci Lab Environm & Biomed Applicat NLEBA, Met Lab 1, Cairo 11757, Egypt
[2] Ain Shams Univ, Fac Educ, Dept Chem, Cairo 11757, Egypt
[3] King Khalid Univ, Fac Sci, Dept Phys, Lab Nanosmart Mat Sci & Technol LNSMST, POB 9004, Abha 61413, Saudi Arabia
[4] King Khalid Univ, Res Ctr Adv Mat Sci RCAMS, POB 9004, Abha 61413, Saudi Arabia
[5] Ain Shams Univ, Fac Educ, Dept Phys, Semicond Lab, Cairo 11757, Egypt
[6] Al Azhar Univ, Fac Sci, Dept Phys, Assiut 71524, Egypt
[7] Beni Suef Univ, Fac Postgrad Studies Adv Sci, Mat Sci & Nanotechnol Dept, Bani Suwayf 62511, Egypt
[8] Arul Anandar Coll, PG & Res Dept Phys, Madurai 625514, Tamil Nadu, India
[9] British Univ Egypt BUE, Nanotechnol Res Ctr NTRC, Suez Desert Rd, Cairo 11837, Egypt
[10] Natl Res Ctr, Spect Dept, Mol Spect & Modeling Unit, 33 El Bohouth St, Giza 12622, Egypt
关键词
Nd2O3 doped CuO nanoparticle; nanostructured photocatalyst; methylene blue; visible light; XRD; SEM; photo-Fenton; EFFICIENT PHOTOCATALYST; INDIGO CARMINE; ND; NANOCOMPOSITE; FABRICATION; EXTRACT; PHOTO; DYE;
D O I
10.3390/nano12071060
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The growth of the textile industry results in a massive accumulation of dyes on water. This enormous rise in pigments is the primary source of water pollution, affecting the aquatic lives and our ecosystem balance. This study aims to notify the fabrication of neodymium incorporated copper oxide (Nd2O3 doped CuO) nanoparticles by combustion method for effective degradation of dye, methylene blue (MB). X-ray diffraction (XRD), Field emission Scanning electron microscopy (FESEM), Zeta potential have been applied for characterization. Photocatalyst validity has been evaluated for methylene blue degradation (MB). Test conditions such as time of contact, H2O2, pH, and photo-Fenton have been modified to identify optimal degradation conditions. Noticeably, 7.5% Nd2O3 doped CuO nanoparticle demonstrated the highest photocatalytic efficiency, up to 90.8% in 80 min, with a 0.0227 min(-1) degradation rate. However, the photocatalytic efficiency at pH 10 becomes 99% with a rate constant of 0.082 min(-1). Cyclic experiments showed the Nd2O3 doped CuO nanoparticle's stability over repeated use. Scavenge hydroxyl radical species responsible for degradation using 7.5% Nd2O3 doped CuO nanoparticles have been investigated under visible irradiation.
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页数:20
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