RESONANT LIGHT-SCATTERING SPECTRA OF MOLECULES WITH DOUBLE-WELL VIBRATIONAL POTENTIALS

被引：0

作者：

Morozov, V. A. ^{[1
]}

Dubina, Yu. M. ^{[2
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Organ Chem Inst, Moscow 119991, Russia

[2] Russian Acad Sci, VA Trapeznikov Inst Control Sci, Moscow 119991, Russia

来源：

JOURNAL OF APPLIED SPECTROSCOPY | 2011年 / 78卷 / 05期

关键词：

excitation spectra of resonant scattering lines; Rayleigh and Raman scattering; double-well potential; hydrogen bond; proton transfer; TRANSITIONS;

D O I：

暂无

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Examples of excitation spectra lines for resonant Rayleigh and Raman scattering by model molecules with a double-well potential in a vibrational subsystem in both the ground and excited states are calculated based on numerical solutions of a stationary Schrodinger equation for a particle in a double-well potential. The obtained results demonstrate that the given formalism can be used, e.g., to establish the mechanism for transferring the proton of an intramolecular H-bond in the excited molecular electronic state upon monochromatic irradiation using resonant light-scattering spectroscopic data.

引用

页码：624 / 630

页数：7

共 14 条

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