Magnetic recyclable Ag catalysts with a hierarchical nanostructure

被引:22
作者
Zhang, Xueping [1 ]
Jiang, Wanquan [1 ]
Zhou, Yufeng [1 ]
Xuan, Shouhu [2 ]
Peng, Chao [2 ]
Zong, Luhang [2 ]
Gong, Xinglong [2 ]
机构
[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
[2] USTC, Dept Modern Mech, CAS Key Lab Mech Behav & Design Mat, Hefei 230027, Peoples R China
关键词
SHELL; NANOPARTICLES; SILICA; REDUCTION; SIZE; PD; MONODISPERSE; FABRICATION; MORPHOLOGY; PARTICLES;
D O I
10.1088/0957-4484/22/37/375701
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This study reports the fabrication of a novel hierarchically structured nanocatalyst system possessing a well-defined nickel silicate (NS) protected Fe3O4 core and a layer of uniform Ag nanoparticles on the NS shell by using a multi-step approach. The multifunctional microparticles show high performance in the reduction of 4-nitrophenol and the rate of the catalytic reaction can be controlled by changing the concentration of nanocatalysts. In particular, there was no visible decrease in the catalytic activity of the reused catalysts even after being recycled five times. Thus the hierarchically structured Fe3O4@NS particles are very suitable as a catalyst support for catalyst separation and redispersion.
引用
收藏
页数:7
相关论文
共 35 条
[1]   Crystallite size and morphology of the phases in Au/TiO2 and Au/Ce-TiO2 catalysts [J].
Bokhimi, Xim ;
Zanella, Rodolfo .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (06) :2525-2532
[2]   Ordered mesoporous silicas and carbons with large accessible pores templated from amphiphilic diblock copolymer poly(ethylene oxide)-b-polystyrene [J].
Deng, Yonghui ;
Yu, Ting ;
Wan, Ying ;
Shi, Yifeng ;
Meng, Yan ;
Gu, Dong ;
Zhang, Lijuan ;
Huang, Yan ;
Liu, Chong ;
Wu, Xiaojing ;
Zhao, Dongyuan .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (06) :1690-1697
[3]   Multifunctional Mesoporous Composite Microspheres with Well-Designed Nanostructure: A Highly Integrated Catalyst System [J].
Deng, Yonghui ;
Cai, Yue ;
Sun, Zhenkun ;
Liu, Jia ;
Liu, Chong ;
Wei, Jing ;
Li, Wei ;
Liu, Chang ;
Wang, Yao ;
Zhao, Dongyuan .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (24) :8466-8473
[4]   Hierarchical magnetite/silica nanoassemblies as magnetically recoverable catalyst-supports [J].
Ge, Jianping ;
Huynh, Tuan ;
Hu, Yongxing ;
Yin, Yadong .
NANO LETTERS, 2008, 8 (03) :931-934
[5]   Ag-Coated Fe3O4@SiO2 Three-Ply Composite Microspheres: Synthesis, Characterization, and Application in Detecting Melamine with Their Surface-Enhanced Raman Scattering [J].
Hu, Haibo ;
Wang, Zhenghua ;
Pan, Ling ;
Zhao, Suping ;
Zhu, Shiyu .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (17) :7738-7742
[6]   An Assembly Route to Inorganic Catalytic Nanoreactors Containing Sub-10-nm Gold Nanoparticles with Anti-Aggregation Properties [J].
Huang, Xiaoqing ;
Guo, Changyou ;
Zuo, Linquan ;
Zheng, Nanfeng ;
Stucky, Galen D. .
SMALL, 2009, 5 (03) :361-365
[7]  
Ikeda S., 2006, ANGEW CHEM, V118, P7221, DOI DOI 10.1002/ANGE.200602700
[8]   Ligand-free platinum nanoparticles encapsulated in a hollow porous carbon shell as a highly active heterogeneous hydrogenation catalyst [J].
Ikeda, Shigeru ;
Ishino, Satoru ;
Harada, Takashi ;
Okamoto, Natsumi ;
Sakata, Takao ;
Mori, Hirotaro ;
Kuwabata, Susumu ;
Torimoto, Tsukasa ;
Matsumura, Michio .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (42) :7063-7066
[9]   Growing small silver particle as redox catalyst [J].
Jana, NR ;
Sau, TK ;
Pal, T .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (01) :115-121
[10]   A novel nanoscale catalyst system composed of nanosized Pd catalysts immobilized on Fe3O4@ SiO2-PAMAM [J].
Jiang, Yijun ;
Jiang, Jinhua ;
Gao, Qiuming ;
Ruan, Meiling ;
Yu, Himei ;
Qi, Lingjun .
NANOTECHNOLOGY, 2008, 19 (07)