Deposition of tetracene thin films on SiO2/Si substrates by rapid expansion of supercritical solutions using carbon dioxide

被引:1
作者
Fujii, Tatsuya [1 ]
Takahashi, Yuta [1 ]
Uchida, Hirohisa [1 ]
机构
[1] Shinshu Univ, Fac Engn, Dept Chem & Mat Engn, Nagano 3808553, Japan
关键词
FIELD-EFFECT TRANSISTORS; POLYMER-COATINGS; MOBILITY; MORPHOLOGY; SURFACES; GROWTH;
D O I
10.7567/APEX.8.035504
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report on a novel deposition technique of tetracene (naphthacene) thin films on SiO2/Si substrates by rapid expansion of supercritical solutions (RESS) using CO2. Optical microscopy and scanning electron microscopy show that the thin films consist of a high density of submicron-sized grains. The growth mode of the grains followed the Volmer-Weber mode. X-ray diffraction shows that the thin films have regularly arranged structures in both the horizontal and vertical directions of the substrate. A fabricated top-contacted organic thin-film transistor with the tetracene active layer showed p-type transistor characteristics with a field-effect mobility of 5.1 x 10(-4)cm(2)V(-1) s(-1). (C) 2015 The Japan Society of Applied Physics
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页数:4
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共 40 条
[1]   Studies of tetracene- and pentacene-based organic thin-film transistors fabricated by the neutral cluster beam deposition method [J].
Abthagir, PS ;
Ha, YG ;
You, EA ;
Jeong, SH ;
Seo, HS ;
Choi, JH .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (50) :23918-23924
[2]   STRUCTURE OF PENTACENE TETRACENE SUPERLATTICES DEPOSITED ON GLASS SUBSTRATE [J].
AKIMICHI, H ;
INOSHITA, T ;
HOTTA, S ;
NOGE, H ;
SAKAKI, H .
APPLIED PHYSICS LETTERS, 1993, 63 (23) :3158-3160
[3]  
[Anonymous], 2011, 13 EUR M SUP FLUIDSS, pCO74
[4]  
[Anonymous], 2012, ORGANIC ELECT
[5]   The larger acenes: Versatile organic semiconductors [J].
Anthony, John E. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (03) :452-483
[6]   Formation of perfluoropolyether coatings by the rapid expansion of supercritical solutions (RESS) process. Part 1: Experimental results [J].
Chernyak, Y ;
Henon, F ;
Harris, RB ;
Gould, RD ;
Franklin, RK ;
Edwards, JR ;
DeSimone, JM ;
Carbonell, RG .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2001, 40 (26) :6118-6126
[7]   Correlation between morphology and field-effect-transistor mobility in tetracene thin films [J].
Cicoira, F ;
Santato, C ;
Dinelli, F ;
Murgia, M ;
Loi, MA ;
Biscarini, F ;
Zamboni, R ;
Heremans, P ;
Muccini, M .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (03) :375-380
[8]   Growth of magnetic thin films using CO2 RESS expansions [J].
De Dea, Silvia ;
Graziani, Dominic ;
Miller, David R. ;
Continetti, Robert E. .
JOURNAL OF SUPERCRITICAL FLUIDS, 2007, 42 (03) :410-418
[9]  
Fujii T., J CHEM ENG IN PRESS
[10]   Thin fluoropolymer films and nanoparticle coatings from the rapid expansion of supercritical carbon dioxide solutions with electrostatic collection [J].
Fulton, JL ;
Deverman, GS ;
Yonker, CR ;
Grate, JW ;
De Young, J ;
McClain, JB .
POLYMER, 2003, 44 (13) :3627-3632