Preparation and Property of Bio-Polyimide/Halloysite Nanocomposite Based on 2,5-Furandicarboxylic Acid

被引：5

作者：

Chen, Yingxia ^{[1
]}

Fan, Shuya ^{[1
]}

Yi, Xibin ^{[2
]}

Li, Bing ^{[2
]}

Chen, Shiwei ^{[1
,2
]}

Liu, Shuyu ^{[1
]}

Hu, Tao ^{[1
]}

Chen, Si ^{[1
]}

机构：

[1] Qilu Univ Technol, Shandong Acad Sci, Sch Mat Sci & Engn, Shandong Prov Key Lab Proc & Testing Technol Glas, Jinan 250353, Peoples R China

[2] Qilu Univ Technol, Shandong Acad Sci, Shandong Key Lab Special Siliconcontaining Mat, Adv Mat Inst, Jinan 250014, Peoples R China

来源：

POLYMERS | 2021年 / 13卷 / 23期

关键词：

bio-based polyimide; halloysite nanotubes; thermal property; mechanical properties; WALLED CARBON NANOTUBES; HALLOYSITE NANOTUBES; BIOBASED POLYIMIDES; THERMAL-PROPERTIES; GRAPHENE; FILM; PERFORMANCE; NANOPARTICLES;

D O I：

10.3390/polym13234057

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Bio-based polyimide (PI)/halloysite nanotube (HNT) nanocomposites based on 2,5-furandicarboxylic acid were prepared by in situ polymerization. The pristine HNTs were modified by tetraethoxysilane (TEOS) and 4,4 '-oxybisbenzenamine (ODA). The bio-based PI/HNT nanocomposite film exhibited lower moisture absorption than pure bio-based polyimide, showing that the water resistance of the bio-based polyimide film was improved. The thermal stability and glass transition temperature (Tg) of PI/HNTs nanocomposites were improved with the addition of modified HNTs. Both the tensile strength and Young's modulus of bio-based PI/HNTs nanocomposite films were enhanced. A 37.7% increase in tensile strength and a 75.1% increase in Young's modulus of bio-based PI/HNTs nanocomposite films, with 1 wt% of the modified HNTs, were achieved. The result confirmed that 2,5-furandicarboxylic acid could replace the oil-based material effectively, thus reducing pollution and protecting the environment. Finally, a preparation mechanism to prepare bio-based PI/HNTs nanocomposite is proposed.

引用

页数：13

共 53 条

[1] Toughening of brittle polyester with functionalized halloysite nanocomposites [J].

Albdiry, M. T. ;

Yousif, B. F. .

COMPOSITES PART B-ENGINEERING, 2019, 160 :94-109

[2] Rod-like attapulgite/polyimide nanocomposites with simultaneously improved strength, toughness, thermal stability and related mechanisms [J].

An, Li ;

Pan, Yongzheng ;

Shen, Xiwen ;

Lu, Hongbin ;

Yang, Yuliang .

JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (41) :4928-4941

[3] Surface modification of natural halloysite clay nanotubes with aminosilanes. Application as catalyst supports in the atom transfer radical polymerization of methyl methacrylate [J].

Barrientos-Ramirez, S. ;

Montes de Oca-Ramirez, G. ;

Ramos-Fernandez, E. V. ;

Sepulveda-Escribano, A. ;

Pastor-Blas, M. M. ;

Gonzalez-Montiel, A. .

APPLIED CATALYSIS A-GENERAL, 2011, 406 (1-2) :22-33

[4] Polysaccharides/Halloysite nanotubes for smart bionanocomposite materials [J].

Bertolino, Vanessa ;

Cavallaro, Giuseppe ;

Milioto, Stefana ;

Lazzara, Giuseppe .

CARBOHYDRATE POLYMERS, 2020, 245

[5] Dispersions of Nanoclays of Different Shapes into Aqueous and Solid Biopolymeric Matrices. Extended Physicochemical Study [J].

Cavallaro, Giuseppe ;

Lazzara, Giuseppe ;

Milioto, Stefana .

LANGMUIR, 2011, 27 (03) :1158-1167

[6] Self-Assembly of Perylene Imide Molecules into 1D Nanostructures: Methods, Morphologies, and Applications [J].

Chen, Shuai ;

Slattum, Paul ;

Wang, Chuanyi ;

Zang, Ling .

CHEMICAL REVIEWS, 2015, 115 (21) :11967-11998

[7] Halloysite nanotubes in polymer science: purification, characterization, modification and applications [J].

Cheng, Cong ;

Song, Weihua ;

Zhao, Qiang ;

Zhang, Hailei .

NANOTECHNOLOGY REVIEWS, 2020, 9 (01) :323-344

[8] Halloysite nanotubes and halloysite-based composites for environmental and biomedical applications [J].

Danyliuk, Nazarii ;

Tomaszewska, Jolanta ;

Tatarchuk, Tetiana .

JOURNAL OF MOLECULAR LIQUIDS, 2020, 309

[9] Polylactic acid (PLA)/halloysite nanotube (HNT) composite mats: Influence of HNT content and modification [J].

Dong, Yu ;

Marshall, Jordan ;

Haroosh, Hazim J. ;

Mohammadzadehmoghadam, Soheila ;

Liu, Dongyan ;

Qi, Xiaowen ;

Lau, Kin-Tak .

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2015, 76 :28-36

[10] High dielectric polyimide composite film filled with a heat-resistant organic salt [J].

Fang, Dan ;

Yao, Kaiqing ;

Ding, Yichun ;

Li, Ping ;

Hou, Haoqing .

COMPOSITES COMMUNICATIONS, 2019, 14 :29-33

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