Efficient Photocatalytic Hydrogen Production in a Single-Component System Using Ru,Rh,Ru Supramolecules Containing 4,7-Diphenyl-1,10-Phenanthroline

被引：59
作者：
White, Travis A. [1 ]
Higgins, Samantha L. H. [1 ]
Arachchige, Shamindri M. [1 ]
Brewer, Karen J. [1 ]
机构：
[1] Virginia Tech, Dept Chem, Blacksburg, VA 24061 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 51期
关键词：
photocatalysis; rhodium; ruthenium; supramolecular complexes; water splitting; PHOTOINITIATED ELECTRON COLLECTION; NAD(+) MODEL LIGAND; ARTIFICIAL PHOTOSYNTHESIS; PHOTOINDUCED REACTIONS; MOLECULAR DEVICE; METAL-COMPLEXES; HYDRIDE DONOR; SOLAR-ENERGY; WATER; RU;
D O I：
10.1002/anie.201105170
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Small changes go a long way: Modification of the terminal ligand to incorporate 4,7-diphenyl-1,10-phenanthroline has generated superior Ru,Rh,Ru photocatalysts (see scheme; ochre Ru, red Rh, blue N, yellow Cl or Br) displaying significantly enhanced photocatalytic H 2 production from H 2O with long-term functioning: H 2O is reduced to H 2 with over 1300 turnovers per Rh site and a maximum efficiency of 7.3-%. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：12209 / 12213
页数：5
相关论文
共 45 条
  • [1] Improved synthetic routes to rhodium bipyridine complexes: Comparison of microwave vs. conventional synthesis
    Amarante, D
    Cherian, C
    Ernmel, C
    Chen, HY
    Dayal, S
    Koshy, M
    Megehee, EG
    [J]. INORGANICA CHIMICA ACTA, 2005, 358 (07) : 2231 - 2238
  • [2] [Anonymous], 2008, ANGEW CHEM
  • [3] Photochemical hydrogen production from water using the new photocatalyst [{(bpy)2Ru(dpp)}2RhBr2](PF6)5
    Arachchige, Shamindri A.
    Brown, Jared
    Brewer, Karen J.
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2008, 197 (01) : 13 - 17
  • [4] High Turnover in a Photocatalytic System for Water Reduction to Produce Hydrogen Using a Ru, Rh, Ru Photoinitiated Electron Collector
    Arachchige, Shamindri M.
    Shaw, Ryan
    White, Travis A.
    Shenoy, Vimal
    Tsui, Hei-Man
    Brewer, Karen J.
    [J]. CHEMSUSCHEM, 2011, 4 (04) : 514 - 518
  • [5] Design Considerations for a System for Photocatalytic Hydrogen Production from Water Employing Mixed-Metal Photochemical Molecular Devices for Photoinitiated Electron Collection
    Arachchige, Shamindri M.
    Brown, Jared R.
    Chang, Eric
    Jain, Avijita
    Zigler, David F.
    Rangan, Krishnan
    Brewer, Karen J.
    [J]. INORGANIC CHEMISTRY, 2009, 48 (05) : 1989 - 2000
  • [6] Luminescent and redox-active polynuclear transition metal complexes
    Balzani, V
    Juris, A
    Venturi, M
    Campagna, S
    Serroni, S
    [J]. CHEMICAL REVIEWS, 1996, 96 (02) : 759 - 833
  • [7] Balzani V., 1987, SUPRAMOLECULAR PHOTO, P1, DOI [10.1007/978-94-009-3979-0_1, DOI 10.1007/978-94-009-3979-0_1, 10.1007/978-94-009-3979-0]
  • [8] ARTIFICIAL PHOTOSYNTHESIS - SOLAR SPLITTING OF WATER TO HYDROGEN AND OXYGEN
    BARD, AJ
    FOX, MA
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (03) : 141 - 145
  • [9] SPECTROSCOPIC AND ELECTROCHEMICAL PROPERTIES OF THE DIMER TETRAKIS(2,2'-BIPYRIDINE)(MU-2,3-BIS(2-PYRIDYL)PYRAZINE)DIRUTHENIUM(II) AND ITS MONOMERIC ANALOG
    BRAUNSTEIN, CH
    BAKER, AD
    STREKAS, TC
    GAFNEY, HD
    [J]. INORGANIC CHEMISTRY, 1984, 23 (07) : 857 - 864
  • [10] MECHANISM OF THE FORMATION OF DIHYDROGEN FROM THE PHOTOINDUCED REACTIONS OF TRIS(BIPYRIDINE)RUTHENIUM(II) WITH TRIS(BIPYRIDINE)RHODIUM(III)
    BROWN, GM
    CHAN, SF
    CREUTZ, C
    SCHWARZ, HA
    SUTIN, N
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (25) : 7638 - 7640
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