Structural analysis of elastically bent organic crystals using in situ indentation and micro-Raman spectroscopy

被引:39
|
作者
Mishra, Manish Kumar [1 ,4 ]
Mishra, Kamini [2 ]
Asif, S. A. Syed [3 ]
Manimunda, Praveena [3 ]
机构
[1] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
[2] Indian Inst Sci, Inorgan & Phys Chem, Bangalore 560012, Karnataka, India
[3] Bruker Nano Surfaces, Minneapolis, MN 55344 USA
[4] Univ Alabama, Dept Chem, Box 870336, Tuscaloosa, AL 35487 USA
关键词
MOLECULAR-CRYSTALS; MECHANICAL-PROPERTIES; NANOINDENTATION; BEHAVIOR; DESIGN;
D O I
10.1039/c7cc08071a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structural dynamics of two elastically bendable, halogenated N-benzylideneaniline organic crystals were studied using an in situ three-point bending test and Raman spectroscopy. This study reveals the inhomogeneous molecular distribution in the elastic crystal lattice during the bent stage and further validates the known qualitative mechanistic model of elastic bendable crystals.
引用
收藏
页码:13035 / 13038
页数:4
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