First cage-like pentanuclear Co(II)-silsesquioxane

被引：38
作者：
Bilyachenko, A. N. [1 ,2 ]
Yalymov, A. I. [1 ]
Levitsky, M. M. [1 ]
Korlyukov, A. A. [1 ,7 ]
Es'kova, M. A. [1 ]
Long, J. [3 ]
Larionova, J. [3 ]
Guari, Y. [3 ]
Shul'pina, L. S. [1 ]
Ikonnikov, N. S. [1 ]
Trigub, A. L. [4 ]
Zubavichus, Y. V. [4 ]
Golub, I. E. [1 ]
Shubina, E. S. [1 ]
Shul'pin, G. B. [5 ,6 ]
机构：
[1] RAS, AN Nesmeyanov Organoelement Cpds Inst, Vavilov Str 28, Moscow, Russia
[2] Peoples Friendship Univ Russia, Miklukho Maklay Str 6, Moscow 117198, Russia
[3] Univ Montpellier, ICGM, UMR5253, Equipe IMNO, Site Triolet,Pl Eugene Bataillon, F-34095 Montpellier 5, France
[4] Kurchatov Inst, Natl Res Ctr, Pl Akad Kurchatova 1, Moscow 123098, Russia
[5] RAS, Semenov Inst Chem Phys, Ul Kosygina,Dom 4, Moscow 119991, Russia
[6] Plekhanov Russian Univ Econ, Stremyannyi Pereulok,Dom 36, Moscow 117997, Russia
[7] Pirogov Russian Natl Res Med Univ, Moscow 117997, Russia
来源：
DALTON TRANSACTIONS | 2016年 / 45卷 / 35期
关键词：
M-CHLOROPERBENZOIC ACID; SINGLE-MOLECULE MAGNET; CRYSTAL-STRUCTURE; OXIDATIVE FUNCTIONALIZATION; CATALYTIC-ACTIVITY; COBALT(II); COMPLEXES; ALKANES; BONDS; SILSESQUIOXANES;
D O I：
10.1039/c6dt02026g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new pentanuclear "cylinder"-like cobalt(II) phenylsilsesquioxane [(PhSiO1.5)(10)(CoO)(5)(NaOH)] exhibits a slow relaxation of the magnetization and a high catalytic activity and stereoselectivity in the oxidation of alkanes and alcohols.
引用
收藏
页码：13663 / 13666
页数：4
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