First cage-like pentanuclear Co(II)-silsesquioxane

被引：38

作者：

Bilyachenko, A. N. ^{[1
,2
]}

Yalymov, A. I. ^{[1
]}

Levitsky, M. M. ^{[1
]}

Korlyukov, A. A. ^{[1
,7
]}

Es'kova, M. A. ^{[1
]}

Long, J. ^{[3
]}

Larionova, J. ^{[3
]}

Guari, Y. ^{[3
]}

Shul'pina, L. S. ^{[1
]}

Ikonnikov, N. S. ^{[1
]}

Trigub, A. L. ^{[4
]}

Zubavichus, Y. V. ^{[4
]}

Golub, I. E. ^{[1
]}

Shubina, E. S. ^{[1
]}

Shul'pin, G. B. ^{[5
,6
]}

机构：

[1] RAS, AN Nesmeyanov Organoelement Cpds Inst, Vavilov Str 28, Moscow, Russia

[2] Peoples Friendship Univ Russia, Miklukho Maklay Str 6, Moscow 117198, Russia

[3] Univ Montpellier, ICGM, UMR5253, Equipe IMNO, Site Triolet,Pl Eugene Bataillon, F-34095 Montpellier 5, France

[4] Kurchatov Inst, Natl Res Ctr, Pl Akad Kurchatova 1, Moscow 123098, Russia

[5] RAS, Semenov Inst Chem Phys, Ul Kosygina,Dom 4, Moscow 119991, Russia

[6] Plekhanov Russian Univ Econ, Stremyannyi Pereulok,Dom 36, Moscow 117997, Russia

[7] Pirogov Russian Natl Res Med Univ, Moscow 117997, Russia

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 35期

关键词：

M-CHLOROPERBENZOIC ACID; SINGLE-MOLECULE MAGNET; CRYSTAL-STRUCTURE; OXIDATIVE FUNCTIONALIZATION; CATALYTIC-ACTIVITY; COBALT(II); COMPLEXES; ALKANES; BONDS; SILSESQUIOXANES;

D O I：

10.1039/c6dt02026g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new pentanuclear "cylinder"-like cobalt(II) phenylsilsesquioxane [(PhSiO1.5)(10)(CoO)(5)(NaOH)] exhibits a slow relaxation of the magnetization and a high catalytic activity and stereoselectivity in the oxidation of alkanes and alcohols.

引用

页码：13663 / 13666

页数：4