First cage-like pentanuclear Co(II)-silsesquioxane

被引：38

作者：

Bilyachenko, A. N. ^{[1
,2
]}

Yalymov, A. I. ^{[1
]}

Levitsky, M. M. ^{[1
]}

Korlyukov, A. A. ^{[1
,7
]}

Es'kova, M. A. ^{[1
]}

Long, J. ^{[3
]}

Larionova, J. ^{[3
]}

Guari, Y. ^{[3
]}

Shul'pina, L. S. ^{[1
]}

Ikonnikov, N. S. ^{[1
]}

Trigub, A. L. ^{[4
]}

Zubavichus, Y. V. ^{[4
]}

Golub, I. E. ^{[1
]}

Shubina, E. S. ^{[1
]}

Shul'pin, G. B. ^{[5
,6
]}

机构：

[1] RAS, AN Nesmeyanov Organoelement Cpds Inst, Vavilov Str 28, Moscow, Russia

[2] Peoples Friendship Univ Russia, Miklukho Maklay Str 6, Moscow 117198, Russia

[3] Univ Montpellier, ICGM, UMR5253, Equipe IMNO, Site Triolet,Pl Eugene Bataillon, F-34095 Montpellier 5, France

[4] Kurchatov Inst, Natl Res Ctr, Pl Akad Kurchatova 1, Moscow 123098, Russia

[5] RAS, Semenov Inst Chem Phys, Ul Kosygina,Dom 4, Moscow 119991, Russia

[6] Plekhanov Russian Univ Econ, Stremyannyi Pereulok,Dom 36, Moscow 117997, Russia

[7] Pirogov Russian Natl Res Med Univ, Moscow 117997, Russia

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 35期

关键词：

M-CHLOROPERBENZOIC ACID; SINGLE-MOLECULE MAGNET; CRYSTAL-STRUCTURE; OXIDATIVE FUNCTIONALIZATION; CATALYTIC-ACTIVITY; COBALT(II); COMPLEXES; ALKANES; BONDS; SILSESQUIOXANES;

D O I：

10.1039/c6dt02026g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new pentanuclear "cylinder"-like cobalt(II) phenylsilsesquioxane [(PhSiO1.5)(10)(CoO)(5)(NaOH)] exhibits a slow relaxation of the magnetization and a high catalytic activity and stereoselectivity in the oxidation of alkanes and alcohols.

引用

页码：13663 / 13666

页数：4

共 50 条

[1] Novel Cage-Like Hexanuclear Nickel(II) Silsesquioxane. Synthesis, Structure, and Catalytic Activity in Oxidations with Peroxides
Bilyachenko, Alexey N.
Yalymov, Alexey I.
Shul'pina, Lidia S.
Mandelli, Dalmo
Korlyukov, Alexander A.
Vologzhanina, Anna V.
Es'kova, Marina A.
Shubina, Elena S.
Levitsky, Mikhail M.
Shul'pin, Georgiy B.
MOLECULES, 2016, 21 (05):
[2] Binuclear Cage-Like Copper(II) Silsesquioxane ("Cooling Tower") - Its High Catalytic Activity in the Oxidation of Benzene and Alcohols
Bilyachenko, Alexey N.
Dronova, Marina S.
Yalymov, Alexey I.
Korlyukov, Alexander A.
Shul'pina, Lidia S.
Arkhipov, Dmitry E.
Shubina, Elena S.
Levitsky, Mikhail M.
Kirilin, Alexey D.
Shul'pin, Georgiy B.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 2013 (30) : 5240 - 5246
[3] Cage-like Copper(II) Silsesquioxanes: Transmetalation Reactions and Structural, Quantum Chemical, and Catalytic Studies
Bilyachenko, Alexey N.
Dronova, Marina S.
Yalymov, Alexey I.
Lamaty, Frederic
Bantreil, Xavier
Martinez, Jean
Bizet, Christelle
Shul'pina, Lidia S.
Korlyukov, Alexander A.
Arkhipov, Dmitry E.
Levitsky, Mikhail M.
Shubina, Elena S.
Kirillov, Alexander M.
Shul'pin, Georgiy B.
CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (24) : 8758 - 8770
[4] Magnetic cage-like metallasilsesquioxanes
Levitsky, Mikhail M.
Bilyachenko, Alexey N.
Shubina, Elena S.
Long, Jerome
Guari, Yannick
Larionova, Joulia
COORDINATION CHEMISTRY REVIEWS, 2019, 398
[5] Cage-like manganesephenylsiloxane with an unusual structure
Bilyachenko, A. N.
Dronova, M. S.
Korlyukov, A. A.
Levitsky, M. M.
Antipin, M. Yu
Zavin, B. G.
RUSSIAN CHEMICAL BULLETIN, 2011, 60 (08) : 1762 - 1765
[6] Preparation of cage-like octa(3-aminopropyl)silsesquioxane trifluoromethanesulfonate in higher yield with a shorter reaction time
Kaneko, Yoshiro
Shoiriki, Miki
Mizumo, Tomonobu
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (29) : 14475 - 14478
[7] Chiral Self-sorting in Cage-like Compounds
Li, Chuanlong
Zuo, Yong
Zhao, You-Quan
Zhang, Shaodong
CHEMISTRY LETTERS, 2020, 49 (11) : 1356 - 1366
[8] Cyclic Water Clusters in Tape-Like and Cage-Like Structures
Huang, Qin
Diao, Lihong
Zhang, Chuang
Lei, Fuhou
MOLECULES, 2011, 16 (04) : 2871 - 2883
[9] Hydrothermal synthesis and characterization of PbS cage-like structures
Huang, Qing-Li
Chen, Hu
Wu, Chang-Le
Zhang, Yong-Cai
MATERIALS LETTERS, 2010, 64 (17) : 1891 - 1893
[10] Two nanosized cage-like Ln20Ni21 clusters exhibiting antiferromagnetic properties
Cui, Chenhui
He, Xingxiang
Lin, Qingfang
Luo, Ximing
Xu, Yan
INORGANIC CHEMISTRY COMMUNICATIONS, 2018, 90 : 101 - 104

← 1 2 3 4 5 →