Photoinduced transformations in low-temperature matrices containing radical cations of organotin compounds

被引：1

作者：

Belokon, EA ^{[1
]}

Pergushov, VI

Tyurin, DA

Egorov, MP

Mel'nikov, MY

机构：

[1] Moscow MV Lomonosov State Univ, Moscow 119992, Russia

[2] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia

来源：

HIGH ENERGY CHEMISTRY | 2005年 / 39卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1007/s10733-005-0046-x

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Charge transfer to matrix molecules was found to be the principal photochemical reaction of the radical cations Me4Sn+center dot and Me6Sn+center dot. It was shown that the difference in the localization of positive charge in the ground state of these radical cations (at the Sn-C bond in Me4Sn+center dot and at the Sn-Sn bond in Me6Sn2+center dot) did not affect the pathways of their photochemical reactions.

引用

页码：224 / 231

页数：8

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