Photoinduced transformations in low-temperature matrices containing radical cations of organotin compounds

被引：1
|
作者：
Belokon, EA [1 ]
Pergushov, VI
Tyurin, DA
Egorov, MP
Mel'nikov, MY
机构：
[1] Moscow MV Lomonosov State Univ, Moscow 119992, Russia
[2] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
来源：
HIGH ENERGY CHEMISTRY | 2005年 / 39卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1007/s10733-005-0046-x
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Charge transfer to matrix molecules was found to be the principal photochemical reaction of the radical cations Me4Sn+center dot and Me6Sn+center dot. It was shown that the difference in the localization of positive charge in the ground state of these radical cations (at the Sn-C bond in Me4Sn+center dot and at the Sn-Sn bond in Me6Sn2+center dot) did not affect the pathways of their photochemical reactions.
引用
收藏
页码：224 / 231
页数：8
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