Platinum Metals in the Catalytic Asymmetric Isomerization of Allylic Alcohols

被引：90
作者：
Mantilli, Luca [1 ]
Mazet, Clement [1 ]
机构：
[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland
来源：
CHEMISTRY LETTERS | 2011年 / 40卷 / 04期
关键词：
JM-PHOS LIGANDS; ENANTIOSELECTIVE ISOMERIZATION; CARBONYL-COMPOUNDS; COMPLEXES; MECHANISM; ALDEHYDES; ROUTE; MEDIA; SCOPE;
D O I：
10.1246/cl.2011.341
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Past and recent advances in the metal-catalyzed asymmetric isomerization of allylic alcohols into carbonyl compounds are discussed in the present Highlight. Emphasis is placed on rhodium, ruthenium, and iridium; the only three metals that have proven successful to date for this most challenging transformation.
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页码：341 / 344
页数：4
相关论文
共 42 条
  • [1] [Anonymous], COMPREHENSIVE ASYMME
  • [2] BAUDRY D, 1978, NOUV J CHIM, V2, P355
  • [3] HOMOGENEOUS CATALYSIS - CATALYTIC PRODUCTION OF SIMPLE ENOLS
    BERGENS, SH
    BOSNICH, B
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (03) : 958 - 967
  • [4] RETRACTED: First rhodium/phosphoramidite complex-catalyzed enantioselective isomerization of allylic alcohols into aldehydes (Retracted article. See vol. 52, pg. 5894, 2011)
    Boeda, Fabien
    Mosset, Paul
    Crevisy, Christophe
    [J]. TETRAHEDRON LETTERS, 2006, 47 (29) : 5021 - 5024
  • [5] BOTTEGHI C, 1976, GAZZ CHIM ITAL, V106, P1131
  • [6] A new enantioselective catalytic route to Florhydral®
    Bovo, Sara
    Scrivanti, Alberto
    Bertoldini, Matteo
    Beghetto, Valentina
    Matteoli, Ugo
    [J]. SYNTHESIS-STUTTGART, 2008, 16 (16): : 2547 - 2550
  • [7] Redox Economy in Organic Synthesis
    Burns, Noah Z.
    Baran, Phil S.
    Hoffmann, Reinhard W.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (16) : 2854 - 2867
  • [8] Bis(allyl)-ruthenium(IV) complexes as highly efficient catalysts for the redox isomerization of allylic alcohols into carbonyl compounds in organic and aqueous media:: Scope, limitations, and theoretical analysis of the mechanism
    Cadierno, V
    García-Garrido, SE
    Gimeno, J
    Varela-Alvarez, A
    Sordo, JA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (04) : 1360 - 1370
  • [9] Ruthenium-catalyzed isomerizations of allylic and propargylic alcohols in aqueous and organic media: Applications in synthesis
    Cadierno, Victorio
    Crochet, Pascale
    Gimeno, Jose
    [J]. SYNLETT, 2008, (08) : 1105 - 1124
  • [10] Chapuis C, 2001, HELV CHIM ACTA, V84, P230, DOI 10.1002/1522-2675(20010131)84:1<230::AID-HLCA230>3.0.CO
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