Platinum Metals in the Catalytic Asymmetric Isomerization of Allylic Alcohols

被引：91

作者：

Mantilli, Luca ^{[1
]}

Mazet, Clement ^{[1
]}

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland

来源：

CHEMISTRY LETTERS | 2011年 / 40卷 / 04期

关键词：

JM-PHOS LIGANDS; ENANTIOSELECTIVE ISOMERIZATION; CARBONYL-COMPOUNDS; COMPLEXES; MECHANISM; ALDEHYDES; ROUTE; MEDIA; SCOPE;

D O I：

10.1246/cl.2011.341

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Past and recent advances in the metal-catalyzed asymmetric isomerization of allylic alcohols into carbonyl compounds are discussed in the present Highlight. Emphasis is placed on rhodium, ruthenium, and iridium; the only three metals that have proven successful to date for this most challenging transformation.

引用

页码：341 / 344

页数：4

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