Synthesis and characterization of the first trimetallic nitride templated pyrrolidino endohedral metallofullerenes

被引:79
作者
Cai, T [1 ]
Ge, ZX [1 ]
Iezzi, EB [1 ]
Glass, TE [1 ]
Harich, K [1 ]
Gibson, HW [1 ]
Dorn, HC [1 ]
机构
[1] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24061 USA
关键词
D O I
10.1039/b503333k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New pyrrolidino derivatives of both diamagnetic and paramagnetic trimetallic nitride templated endohedral metallofullerenes were synthesized by the Prato reaction, isolated and characterized by means of MALDI-TOF MS, NMR and UV vis spectroscopies.
引用
收藏
页码:3594 / 3596
页数:3
相关论文
共 19 条
[1]   Kinetic stability of metallofullerenes as predicted by the bond resonance energy model [J].
Aihara, J .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (08) :1427-1431
[2]   Kinetic stability of carbon cages in non-classical metallofullerenes [J].
Aihara, J .
CHEMICAL PHYSICS LETTERS, 2001, 343 (5-6) :465-469
[3]   EXOHEDRAL DERIVATIZATION OF AN ENDOHEDRAL METALLOFULLERENE GD-AT-C-82 [J].
AKASAKA, T ;
NAGASE, S ;
KOBAYASHI, K ;
SUZUKI, T ;
KATO, T ;
YAMAMOTO, K ;
FUNASAKA, H ;
TAKAHASHI, T .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (13) :1343-1344
[4]   First soluble M@C60 derivatives provide enhanced access to metallofullerenes and permit in vivo evaluation of Gd@C60[C(COOH)2]10 as a MRI contrast agent [J].
Bolskar, RD ;
Benedetto, AF ;
Husebo, LO ;
Price, RE ;
Jackson, EF ;
Wallace, S ;
Wilson, LJ ;
Alford, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (18) :5471-5478
[5]   NUCLEAR MAGNETIC-RESONANCE SPECTRA OF CYCLIC AMINES - SHIELDING OF ALPHA-PROTONS TRANS TO A LONE PAIR AND CIS TO AN N-METHYL GROUP IN PYRROLIDINES [J].
BREUER, E ;
MELUMAD, D .
JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (08) :1601-1602
[6]   Lanthanum endohedral metallofulleropyrrolidines: Synthesis, isolation, and EPR characterization [J].
Cao, BP ;
Wakahara, T ;
Maeda, Y ;
Han, AH ;
Akasaka, T ;
Kato, T ;
Kobayashi, K ;
Nagase, S .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (03) :716-720
[7]   REPULSION OF SYN-AXIAL ELECTRON PAIRS . RABBIT-EAR EFFECT [J].
HUTCHINS, RO ;
KOPP, LD ;
ELIEL, EL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (25) :7174-&
[8]   A symmetric derivative of the trimetallic nitride endohedral metallofullerene, Sc3N@C80 [J].
Iezzi, EB ;
Duchamp, JC ;
Harich, K ;
Glass, TE ;
Lee, HM ;
Olmstead, MM ;
Balch, AL ;
Dorn, HC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (04) :524-525
[9]   Lutetium-based trimetallic nitride endohedral metallofullerenes: New contrast agents [J].
Iezzi, EB ;
Duchamp, JC ;
Fletcher, KR ;
Glass, TE ;
Dorn, HC .
NANO LETTERS, 2002, 2 (11) :1187-1190
[10]   Lanthanoid endohedral metallofullerenols for MRI contrast agents [J].
Kato, H ;
Kanazawa, Y ;
Okumura, M ;
Taninaka, A ;
Yokawa, T ;
Shinohara, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (14) :4391-4397