Many-body effects in molecular photoionization in intense laser fields; time-dependent Hartree-Fock simulations

被引:18
作者
Suzuki, M
Mukamel, S
机构
[1] Osaka City Univ, Grad Sch Sci, Dept Phys, Sumiyoshi Ku, Osaka 5588585, Japan
[2] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
[3] Univ Rochester, Dept Phys & Astron, Rochester, NY 14627 USA
关键词
D O I
10.1063/1.1631252
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The time evolution of the reduced single electron density matrix for eight electrons in a one-dimensional finite box potential driven by an intense laser field is calculated by numerically integrating the time-dependent Hartree-Fock equations. We study the effects of the Coulomb interaction, field intensity, and frequency on the time profile of the ionization process. Our computed saturation ionization intensity (I-sat) is in good agreement with experimental results for decatetraene [Ivanov J. Chem. Phys. 117, 1575 (2002)]. (C) 2004 American Institute of Physics.
引用
收藏
页码:669 / 676
页数:8
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