Twelve-connected net with face-centered cubic topology:: A coordination polymer based on [Cu12(μ4-SCH3)6]6+ clusters and CN- linkers

被引：217
作者：
Li, D [1 ]
Wu, T
Zhou, XP
Zhou, R
Hitang, XC
机构：
[1] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China
[2] Shantou Univ, Coll Med, Dept Chem, Shantou 515063, Guangdong, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 27期
关键词：
cluster compounds; copper; S ligands; solvothermal synthesis; topological networks;
D O I：
10.1002/anie.200500290
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Globular configuration: a microporous coordination polymer based on a dodecanuclear copper(I) cluster (picture: C black, Cu red, N blue, S yellow) as a twelve-connected node, was synthesized by a simultaneous redox, sulfurization, and self-assembly reaction under solvothermal conditions. The synthesis provides a model reaction to simulate the transformation of inorganic sulfur into organic sulfur. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：4175 / 4178
页数：4
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