Effect of Excess MgO Mole Ratio in a Stoichiometric Cordierite (2MgO•2Al2O3•5SiO2) Composition on the Phase Transformation and Crystallization Behavior of Magnesium Aluminum Silicate Phases

被引：32

作者：

Banjuraizah, Johar ^{[1
]}

Mohamad, Hasmaliza ^{[2
]}

Ahmad, Zainal Arifin ^{[2
]}

机构：

[1] Univ Malaysia Perlis, Sch Mat Engn, Kangar 02600, Perlis, Malaysia

[2] Univ Sains Malaysia, Sch Mat & Mineral Resources Engn, Nibong Tebal 14300, Penang, Malaysia

来源：

INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY | 2011年 / 8卷 / 03期

关键词：

GLASS-CERAMICS; POWDER; TALC; CEO2;

D O I：

10.1111/j.1744-7402.2010.02486.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The effect of excess MgO, 2.0-4.0 mol ratios on the crystallization behavior and purity of mu-cordierite was investigated using X-ray diffraction (XRD), differential thermal analyzer, and TGA. Quantitative XRD, the Rietveld technique, was carried out using the HighScore Plus software. The glass crystallization process route was used with talc and kaolin as the main raw materials and compensated with MgO, Al2O3, and SiO2 accordingly. The crystallization temperature of the glasses decreased as a function of the MgO mole ratio. Less than 2.8 mol MgO increased the formation of alpha-cordierite up to 94 wt%. However, above 2.8 mol ratio, the forsterite phase started to appear, together with mullite, mu-cordierite, and spinel.

引用

页码：637 / 645

页数：9

共 24 条

[1] Synthesis and characterization of the cordierite ceramics from nonstandard raw materials for application in foundry
Acimovic, Z
Pavlovic, L
Trumbulovic, L
Andric, L
Stamatovic, M
[J]. MATERIALS LETTERS, 2003, 57 (18) : 2651 - 2656
[2] AMISTA P, 1995, J NON-CRYST SOLIDS, V193, P529
[3] Sintering, crystallization, and properties of CaO doped cordierite-based glass-ceramics
Chen, Guo-hua
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 455 (1-2) : 298 - 302
[4] Sintering, crystallization and properties of MgO-Al2O3-SiO2 system glass-ceramics containing ZnO
Chen, Guo-Hua
Liu, Xin-Yu
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 431 (1-2) : 282 - 286
[5] CORRECTION OF INTENSITIES FOR PREFERRED ORIENTATION IN POWDER DIFFRACTOMETRY - APPLICATION OF THE MARCH MODEL
DOLLASE, WA
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1986, 19 (pt 4) : 267 - 272
[6] Glendenning MD, 1996, J AM CERAM SOC, V79, P705, DOI 10.1111/j.1151-2916.1996.tb07933.x
[7] Non-isothermal crystallization kinetic studies on MgO-Al2O3-SiO2-TiO2 glass
Goel, A.
Shaaban, E. R.
Melo, F. C. L.
Ribeiro, M. J.
Ferreira, J. M. F.
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2007, 353 (24-25) : 2383 - 2391
[8] Influence of particle size distribution of precursor oxides on the synthesis of cordierite by solid-state reaction
González-Velasco, JR
Ferret, R
López-Fonseca, R
Gutiérrez-Ortiz, MA
[J]. POWDER TECHNOLOGY, 2005, 153 (01) : 34 - 42
[9] Synthesis of cordierite powder from talc, diatomite and alumina
Goren, R
Gocmez, H
Ozgur, C
[J]. CERAMICS INTERNATIONAL, 2006, 32 (04) : 407 - 409
[10] The preparation of cordierite from talc, fly ash, fused silica and alumina mixtures
Goren, R
Ozgur, C
Gocmez, H
[J]. CERAMICS INTERNATIONAL, 2006, 32 (01) : 53 - 56

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