Development of thermoplastic elastomers based on maleated ethylene propylene rubber (m-EPM) and polypropylene (PP) by dynamic vulcanization

被引:55
作者
Chatterjee, K. [1 ]
Naskar, K. [1 ]
机构
[1] Indian Inst Technol, Ctr Rubber Technol, Kharagpur 721302, W Bengal, India
关键词
polymer blends and alloys; maleated ethylene propylene rubber; polypropylene; dynamic vulcanization; peroxide;
D O I
10.3144/expresspolymlett.2007.75
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Dicumyl peroxide (DCP)-cured thermoplastic vulcanizates (TPVs) based on blends of maleated ethylene propylene rubber (m-EPM) and polypropylene (PP) using maleated-PP as a compatibilizer have been developed. Physical properties of these TPVs change significantly with concentrations of DCP and rubber/plastic blend ratios. Important correlations were obtained from rheometer delta torque values with various physical properties of the TPVs like tension set and crosslink density etc. Wide angle X-ray diffraction study confirms that concentration of DCP has a strong influence on the crystallinity of PP, which might affect the final physical properties of TPVs. The recyclability and ageing characteristics of these TPVs are also found excellent.
引用
收藏
页码:527 / 534
页数:8
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