Effect of wet spinning parameters on the properties of novel cellulosic fibres

被引:64
作者
Vehvilainen, Marianna [1 ]
Kamppuri, Taina [1 ]
Rom, Monika [2 ]
Janicki, Jaroslaw [2 ]
Ciechanska, Danuta [3 ]
Gronqvist, Stina [4 ]
Siika-Aho, Matti [4 ]
Christoffersson, Kristina Elg [5 ]
Nousiainen, Pertti [1 ]
机构
[1] Tampere Univ Technol, FIN-33101 Tampere, Finland
[2] Univ Bielsko Biala, Inst Textile Engn & Polymer Mat, Fac Mat & Environm Sci, Bielsko Biala, Poland
[3] Inst Biopolymers & Chem Fibres, Dept Fibres Nat Polymers, Lodz, Poland
[4] VTT Tech Res Ctr Finland, VTT Biotechnol, Espoo, Finland
[5] Domsjo Fabriker Ab, Ornskoldsvik, Sweden
关键词
biocelsol; cellulases; cellulosic fibres; directly alkaline soluble cellulose; dissolving pulp; enzymatic treatment of cellulose;
D O I
10.1007/s10570-008-9219-3
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
Novel cellulose fibres (Biocelsol) were spun by traditional wet spinning technique from the alkaline solution prepared by dissolving enzyme treated pulp directly into aqueous sodium zincate (ZnO/NaOH). The spinning dope contained 6 wt.% of cellulose, 7.8 wt.% of sodium hydroxide (NaOH) and 0.84 wt.% of zinc oxide (ZnO). The fibres were spun into 5% and 15% sulphuric acid (H(2)SO(4)) baths containing 10% sodium sulphate (Na(2)SO(4)). The highest fibre tenacity obtained was 1.8 cNdtex(-1) with elongation of 15% and titre of 1.4 dtex. Average molecular weights and shape of molecular weight distribution curves of the celluloses from the novel wet spun cellulosic fibre and from the commercial viscose fibre were close to each other.
引用
收藏
页码:671 / 680
页数:10
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