Low-cost synthesis of graphitic carbon nanofibers as excellent room temperature sensors for explosive gases

被引:105
作者
Li, Wei [1 ,2 ]
Zhang, Le-Sheng [1 ,2 ]
Wang, Qiong [1 ]
Yu, Yu [1 ,2 ]
Chen, Zhe [1 ,2 ]
Cao, Chang-Yan [1 ]
Song, Wei-Guo [1 ]
机构
[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci BNLMS, Inst Chem, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
TIN OXIDE NANOCRYSTALS; CHEMICAL SENSORS; VAPOR SENSORS; NANOTUBES; GRAPHENE; SENSITIVITY; NANOPARTICLES; METAL; FABRICATION; NANOBELTS;
D O I
10.1039/c2jm32031b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
With greatly enhanced surface-to-volume ratios, one-dimensional (1D) carbon nanostructures are believed to be able to deliver superior performance as room temperature sensors for explosive gases. 1D carbon nanofibers composed of graphitic nanorolls were prepared using a simple electrospinning-assisted solid-phase graphitization method. This method is facile and low cost and can allow high-yield production of carbon nanofibers. The unique structure of the as-prepared graphitic carbon nanofibers is different from that of conventional 1D carbon nanostructures. It offers the optimal balance between conductivity and adsorption capacity for gas sensing and thus results in remarkable gas-sensing properties in detecting explosive gases including H-2, CO, CH4 and ethanol at room temperature.
引用
收藏
页码:15342 / 15347
页数:6
相关论文
共 47 条
[1]   Enhanced CO sensitivity and selectivity of gold nanoparticles-doped SnO2 sensor in presence of propane and methane [J].
Bahrami, B. ;
Khodadadi, A. ;
Kazemeini, M. ;
Mortazavi, Y. .
SENSORS AND ACTUATORS B-CHEMICAL, 2008, 133 (01) :352-356
[2]   Sensitivity to NO2 and cross-sensitivity analysis to NH3, ethanol and humidity of carbon nanotubes thin film prepared by PECVD [J].
Cantalini, C ;
Valentini, L ;
Armentano, I ;
Lozzi, L ;
Kenny, JM ;
Santucci, S .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 95 (1-3) :195-202
[3]   α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications [J].
Chen, J ;
Xu, LN ;
Li, WY ;
Gou, XL .
ADVANCED MATERIALS, 2005, 17 (05) :582-+
[4]   Stable and highly sensitive gas sensors based on semiconducting oxide nanobelts [J].
Comini, E ;
Faglia, G ;
Sberveglieri, G ;
Pan, ZW ;
Wang, ZL .
APPLIED PHYSICS LETTERS, 2002, 81 (10) :1869-1871
[5]   Adsorption and dissociation of hydrogen molecules on bare and functionalized carbon nanotubes [J].
Dag, S ;
Ozturk, Y ;
Ciraci, S ;
Yildirim, T .
PHYSICAL REVIEW B, 2005, 72 (15)
[6]   Thermal stabilization of polyacrylonitrile fibres [J].
Dalton, S ;
Heatley, F ;
Budd, PM .
POLYMER, 1999, 40 (20) :5531-5543
[7]   Practical Chemical Sensors from Chemically Derived Graphene [J].
Fowler, Jesse D. ;
Allen, Matthew J. ;
Tung, Vincent C. ;
Yang, Yang ;
Kaner, Richard B. ;
Weiller, Bruce H. .
ACS NANO, 2009, 3 (02) :301-306
[8]   Metal and metal oxide nanoparticles in chemiresistors: Does the nanoscale matter? [J].
Franke, ME ;
Koplin, TJ ;
Simon, U .
SMALL, 2006, 2 (01) :36-50
[9]   Differentiation of gas molecules using flexible and all-carbon nanotube devices [J].
Fu, Dongliang ;
Lim, Hueiling ;
Shi, Yumeng ;
Dong, Xiaochen ;
Mhaisalkar, S. G. ;
Chen, Yuan ;
Moochhala, Shabbir ;
Li, Lain-Jong .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (03) :650-653
[10]   Carbon nanotubes on carbon nanofibers: A novel structure based on electrospun polymer nanofibers [J].
Hou, HQ ;
Reneker, DH .
ADVANCED MATERIALS, 2004, 16 (01) :69-+