Preparation, crystal structure, and magnetism of [(CH3)2NH2][NdCl4(H2O)2]

被引：0

作者：

Becker, A ^{[1
]}

Urland, W ^{[1
]}

机构：

[1] Univ Hannover, Inst Anorgan Chem, D-30167 Hannover, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 02期

关键词：

dimethylammonium diaquatetrachloroneodymate; crystal structure; magnetic properties; angular overlap model;

D O I：

10.1002/(SICI)1521-3749(199902)625:2<217::AID-ZAAC217>3.0.CO;2-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex water containing chloride [(CH3)(2)NH2] [NdCl4(H2O)(2)] was prepared for the first time and the crystal structure was determined by X-ray methods from single crystals. The compound crystallizes in the orthorhombic space group Cmca (Z = 8) with a = 1793.5(2) pm, b = 936.6(2) pm and c = 1232.8(2) pm. The anionic part of the structure is built up by chains of edge connected [NdCl4/2Cl2(H2O)(2)](-) trigondodecahedra. In order to study the interactions between the neodymium cation and the ligands magnetic measurements were carried out. The magnetic data were interpreted by ligand field calculations applying the angular overlap model.

引用

页码：217 / 220

页数：4

共 50 条

[31] Neptunium(VI) chromate complex with 1,2-diammoniopropane {H3NCH2CH(NH3)CH3}[(NpO2)2(CrO4)3(H2O)] • 3H2O:: Synthesis, crystal structure and properties
Budantseva, NA
Andreev, GB
Fedoseev, AM
Antipin, MY
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2003, 29 (09) : 653 - 657
[32] A novel chain-like molybdenum phosphate: hydrothermal synthesis, crystal structure and characterization of [NH3(CH2CH2)2NH3]3[NH3(CH2CH2)2NH2]-Na5[Mo6O12(OH)3(PO4)(HPO4)3]2·4H2O
Shutao Wang
Enbo Wang
Yu Hou
Yangguang Li
Li Wang
Mei Yuan
Changwen Hu
Transition Metal Chemistry, 2003, 28 : 616 - 620
[33] Preparation and crystal structure of a charge-transfer complex between an organic substrate and molybdosilicic acid [(CH3)2NH(CH2)C6H5]4SiMo12O40•2CH3CN•H2O
Wang, JP
Han, QX
Niu, JY
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (11) : 1246 - 1251
[34] Preparation and Crystal Structure of a Charge-transfer Complex between an Organic Substrate and Molybdosilicic Acid [（CH3）2NH（CH2）C6H5]4SiMo12O40·2CH3CN·H2O
WANG Jing-Ping HAN Qiu-Xia NIU Jing-Yang② (School of Chemistry and Chemical Engineering
结构化学, 2004, (11) : 1246 - 1251
[35] Optical, electrical properties and conduction mechanism of [(CH3)2NH2]2ZnCl4 compound
Mahfoudh, N.
Karoui, K.
Khirouni, K.
Ben Rhaiem, A.
PHYSICA B-CONDENSED MATTER, 2019, 554 (126-136) : 126 - 136
[36] Synthesis, characterisation, structure, and magnetic properties of [Ni{H2NCH(CH3)CH2NH2}3][Fe(CN)5NO]•H2O
Saha, MK
Dey, DK
Samanta, B
Dey, SK
Malik, KMA
Mitra, S
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2005, 60 (10): : 1043 - 1048
[37] Neptunium(VI) Chromate Complex with 1,2-Diammoniopropane {H3NCH2CH(NH3)CH3}[(NpO2)2(CrO4)3(H2O)] · 3H2O: Synthesis, Crystal Structure and Properties
N. A. Budantseva
G. B. Andreev
A. M. Fedoseev
M. Yu. Antipin
Russian Journal of Coordination Chemistry, 2003, 29 : 653 - 657
[38] Crystal Structure of [UO2SO4{(CH3)HNCONH(CH3)}2]
L. B. Serezhkina
E. V. Mit'kovskaya
I. V. Medrish
E. V. Grechishnikova
F. M. Dolgushin
M. Yu. Antipin
V. N. Serezhkin
Russian Journal of Coordination Chemistry, 2005, 31 : 889 - 893
[39] Preparation, crystal structure and thermal stability of [(CH3)4N]2[Co(H2O)6](SeO4)2•4H2O: A hydrogen bond stabilized hydrated double selenate
Divekar, Sandesh K.
Achary, S. Nagabhusan
Ajgaonkar, Vishnu R.
SOLID STATE SCIENCES, 2021, 122
[40] Preparation, crystal structure and thermodynamical properties of [Sr(NTO)2(H2O)4]2•4H2O
Song, JR
Hu, RZ
Li, FP
Yu, KB
ACTA CHIMICA SINICA, 2000, 58 (02) : 222 - 228

← 1 2 3 4 5 →