Construction of Anti-Ultraviolet "Shielding Clothes" on Poly(p-phenylene benzobisoxazole) Fibers: Metal Organic Framework-Mediated Absorption Strategy

被引：63

作者：

Hu, Zhen ^{[1
]}

Lu, Fei ^{[1
]}

Liu, Yingying ^{[1
]}

Zhao, Lei ^{[1
]}

Yu, Long ^{[1
]}

Xu, Xirong ^{[1
]}

Yuan, Weihao ^{[1
]}

Zhang, Qian ^{[1
]}

Huang, Yudong ^{[1
]}

机构：

[1] Harbin Inst Technol, MIIT Key Lab Crit Mat Technol New Energy Convers, Sch Chem & Chem Engn, Harbin 150001, Heilongjiang, Peoples R China

来源：

ACS APPLIED MATERIALS & INTERFACES | 2018年 / 10卷 / 49期

基金：

中国国家自然科学基金;

关键词：

PBO fibers; metal-organic-frameworks; adsorption strategy; anti-UV property; synergistic effects; PBO FIBERS; AGING RESISTANCE; SOLVOTHERMAL SYNTHESIS; SELECTIVE ADSORPTION; AQUEOUS-SOLUTION; MOFS; UIO-66; REMOVAL; SURFACE; WATER;

D O I：

10.1021/acsami.8b16845

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A metal organic framework (MOF)-mediated adsorption strategy is first developed for improving the anti ultraviolet (UV) properties of poly(p-phenylene benzobisoxazole) (PBO) fibers. In this work, UIO-66 was successfully anchored onto the surface of PBO fibers by one-step microwave-assisted heating method. The experimental results showed an obviously enhanced surface energy (91.1%), roughness (268.4%), interfacial shear strength (49.0%), and anti-UV properties (66.7%) compared to pristine PBO fibers. The anti-UV dye (tartrazine) was further immobilized onto the surface of PBO fibers via an adsorption strategy mediated by UIO-66. Interestingly, the PBO@tartrazine fibers demonstrated superior anti-UV performance (further up to 81.5%) compared to PBO@UIO-66 fibers. The extraordinary anti-UV properties of PBO@ tartrazine fibers could be rationally ascribed to the synergistic effects of UIO-66 and tartrazine molecules. Considering the diversities and functionalities of MOFs and targeted materials, our work indicates that the MOF-mediated adsorption strategy would promisingly endow PBO fibers with other desired performance and applications such as solar-thermal transition and self-healing abilities.

引用

页码：43262 / 43274

页数：13

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