Synthesis of multifunctional microspheres having polymer brush with magnetism, fluorescence, and pH-responsiveness

被引：4

作者：

Liu, Tuanwei ^{[1
]}

Liu, Bin ^{[1
]}

Fu, Xiaomeng ^{[1
]}

Sun, Shuxuan ^{[1
]}

Liu, Wei ^{[2
]}

Bian, Guomin ^{[3
]}

Qi, Yonglin ^{[3
]}

Yang, Xinlin ^{[1
]}

机构：

[1] Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Inst Polymer Chem, Key Lab Funct Polymer Mat,Minist Educ, Tianjin 300071, Peoples R China

[2] Tianjin Polytech Univ, Sch Environm & Chem Engn, State Key Lab Hollow Fiber Membrane Mat & Proc, Tianjin 300387, Peoples R China

[3] Dynea Ltd Co, Gaoyao City 526105, Guangdong, Peoples R China

来源：

COLLOID AND POLYMER SCIENCE | 2015年 / 293卷 / 03期

关键词：

Magnetic nanoparticles; Fluorescent nanoparticles; Surface-initiated ATRP; pH-responsive nanoparticles; IRON-OXIDE NANOPARTICLES; CORE; RELEASE; DRUG;

D O I：

10.1007/s00396-014-3469-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Multifunctional magnetite@silica-fluorescein isothioxylate-g-poly(dimethyl amino ethyl methacrylate) (Fe3O4@SiO2-FITC-g-PDMAEMA) tri-layer microspheres with magnetism, fluorescence, and pH-responsive PDMAEMA shell were designed and prepared. The functional PDMAEMA brush was grafted from Fe3O4@SiO2-FITC nanoparticles by the surface-induced atom transfer radical polymerization (SI-ATRP) onto the alkylbromide-modified Fe3O4@SiO2-FITC fluorescent templates, which were synthesized by the co-precipitation of Fe(II) and Fe(III) under basic condition together with the subsequently modified Stober sol-gel technique. These nanoparticles were characterized by transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), fluorescence spectrum, dynamic light scattering (DLS), and zeta potentials.

引用

页码：809 / 816

页数：8

共 4 条

[1] Synthesis of multifunctional microspheres having polymer brush with magnetism, fluorescence, and pH-responsiveness
Tuanwei Liu
Bin Liu
Xiaomeng Fu
Shuxuan Sun
Wei Liu
Guomin Bian
Yonglin Qi
Xinlin Yang
Colloid and Polymer Science, 2015, 293 : 809 - 816
[2] Synthesis and Characterization of MNPs Hydrogel with pH-Responsiveness Properties to Release Diclofenac Sodium as a Model Drug
Ghobadifar, Vahid
Marandi, Gholam Bagheri
Kurdtabar, Mehran
Bardajee, Ghasem Rezanejad
IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION, 2023, 42 (03): : 875 - 889
[3] RAFT polymerization of methacrylates containing a tryptophan moiety: controlled synthesis of biocompatible fluorescent cationic chiral polymers with smart pH-responsiveness
Roy, Saswati Ghosh
Acharya, Rituparna
Chatterji, Urmi
De, Priyadarsi
POLYMER CHEMISTRY, 2013, 4 (04) : 1141 - 1152
[4] Synthesis of pH-sensitive hollow polymer microspheres and their application as drug carriers
Yang, Xiaoying
Chen, Liting
Huang, Bo
Bai, Feng
Yang, Xinlin
POLYMER, 2009, 50 (15) : 3556 - 3563

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