Recent Advances of Manganese Catalysis for Organic Synthesis

被引：228

作者：

Carney, Jonathan R. ^{[1
]}

Dillon, Barry. R. ^{[2
]}

Thomas, Stephen P. ^{[1
]}

机构：

[1] Univ Edinburgh, EaStCHEM Sch Chem, Joseph Black Bldg,David Brewster Rd, Edinburgh EH9 3FJ, Midlothian, Scotland

[2] AstraZeneca, Alderley Pk, Macclesfield SK10 4TG, Cheshire, England

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 2016卷 / 23期

关键词：

Homogeneous catalysis; Manganese; C-H activation; Fluorination; CROSS-COUPLING REACTION; C-H HYDROXYLATION; MN-III CATALYST; 1,3-DICARBONYL COMPOUNDS; GRIGNARD-REAGENTS; HIGHLY EFFICIENT; ALPHA; BETA-UNSATURATED KETONES; CARBONYL-COMPLEXES; HYDROSILYLATION; OXIDATION;

D O I：

10.1002/ejoc.201600018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Manganese is a non-toxic, inexpensive and earth abundant metal, so is a perfect candidate for catalysis whether as a replacement for precious metals or in the search for novel reactivity. Despite this, manganese catalysis has not undergone the same development of other earth-abundant metals (particularly iron and cobalt). This review details recent synthetic methodologies using manganese catalysts, including C-H activation, late stage fluorination, hydrosilylation and cross-coupling.

引用

页码：3912 / 3929

页数：18

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