Constructing three-dimensional boron nitride network for highly thermally conductive epoxy resin composites

被引:45
作者
Wu, Xian [1 ]
Liu, Wei [1 ]
Shi, Fa-guo [2 ]
Yang, Le [1 ]
Zhang, Chun [1 ]
机构
[1] Guizhou Inst Technol, Sch Mat & Energy Engn, Guiyang 550003, Peoples R China
[2] Guizhou Yong Hong Aviat Machinery Co Ltd, Guiyang, Peoples R China
基金
中国国家自然科学基金;
关键词
boron nitride; epoxy resin; thermal conductive network; thermal conductivity; NATURAL-RUBBER; FILMS;
D O I
10.1002/pc.26490
中图分类号
TB33 [复合材料];
学科分类号
摘要
Construction of heat conduction channels in polymer matrix plays a key role in thermally conductive composite. In this work, three-dimensional (3D) boron nitride (BN) framework was successfully fabricated by decomposing the sacrificial material. The resultant 3D-BN framework with honeycomb-like structure was further infiltrated with liquid epoxy resin. With the aid of thermally conductive pathways formed by the 3D-BN framework, the maximum thermal conductivity of EP/3D-BN composites reaches 3.53 W/m center dot K with 55.85 vol% BN, which is 17.6 times larger than that of pure EP. The EP/3D-BN composites demonstrate strong capability to dissipate the heat during heating and cooling processes. This work provides a facile method for developing thermal conductive composites applied in thermal management for electronics.
引用
收藏
页码:1711 / 1717
页数:7
相关论文
共 43 条
[1]   Construction of 3D boron nitride nanosheets/silver networks in epoxy-based composites with high thermal conductivity via in-situ sintering of silver nanoparticles [J].
Chen, Chao ;
Xue, Yang ;
Li, Zhi ;
Wen, Yingfeng ;
Li, Xiongwei ;
Wu, Fan ;
Li, Xiaojing ;
Shi, Dean ;
Xue, Zhigang ;
Xie, Xiaolin .
CHEMICAL ENGINEERING JOURNAL, 2019, 369 :1150-1160
[2]   Cellulose Nanofiber Supported 3D Interconnected BN Nanosheets for Epoxy Nanocomposites with Ultrahigh Thermal Management Capability [J].
Chen, Jin ;
Huang, Xingyi ;
Zhu, Yingke ;
Jiang, Pingkai .
ADVANCED FUNCTIONAL MATERIALS, 2017, 27 (05)
[3]  
Chen X., 2020, MAT INTERFACES, V12, P16987
[4]   Constructing a "pea-pod-like" alumina-graphene binary architecture for enhancing thermal conductivity of epoxy composite [J].
Chen, Yapeng ;
Hou, Xiao ;
Liao, Meizhen ;
Dai, Wen ;
Wang, Zhongwei ;
Yan, Chao ;
Li, He ;
Lin, Cheng-Te ;
Jiang, Nan ;
Yu, Jinhong .
CHEMICAL ENGINEERING JOURNAL, 2020, 381
[5]   Largely improved thermal conductivity of PI/BNNS nanocomposites obtained by constructing a 3D BNNS network and filling it with AgNW as the thermally conductive bridges [J].
Dong, Jie ;
Cao, Lei ;
Li, Yun ;
Wu, Zhiqiang ;
Teng, Cuiqing .
COMPOSITES SCIENCE AND TECHNOLOGY, 2020, 196
[6]   Simultaneous improvement of thermal conductivities and electromagnetic interference shielding performances in polystyrene composites via constructing interconnection oriented networks based on electrospinning technology [J].
Guo, Yongqiang ;
Pan, Lulu ;
Yang, Xutong ;
Ruan, Kunpeng ;
Han, Yixin ;
Kong, Jie ;
Gu, Junwei .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2019, 124
[7]   Enhanced thermal conductivity by constructing 3D-networks in poly (vinylidene fluoride) composites via positively charged hexagonal boron nitride and silica coated carbon nanotubes [J].
Hu, Boyang ;
Guo, Hong ;
Wang, Qin ;
Zhang, Wei ;
Song, Shasha ;
Li, Xipeng ;
Li, Yi ;
Li, Baoan .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2020, 137
[8]   Polymer Composite with Improved Thermal Conductivity by Constructing a Hierarchically Ordered Three-Dimensional Interconnected Network of BN [J].
Hu, Jiantao ;
Huang, Yun ;
Yao, Yimin ;
Pan, Guiran ;
Sun, Jiajia ;
Zeng, Xiaoliang ;
Sun, Rong ;
Xu, Jian-Bin ;
Song, Bo ;
Wong, Ching-Ping .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (15) :13544-13553
[9]   A novel approach for Al2O3/epoxy composites with high strength and thermal conductivity [J].
Hu, Yong ;
Du, Guoping ;
Chen, Nan .
COMPOSITES SCIENCE AND TECHNOLOGY, 2016, 124 :36-43
[10]   Polyhedral Oligosilsesquioxane-Modified Boron Nitride Nanotube Based Epoxy Nanocomposites: An Ideal Dielectric Material with High Thermal Conductivity [J].
Huang, Xingyi ;
Zhi, Chunyi ;
Jiang, Pingkai ;
Golberg, Dmitri ;
Bando, Yoshio ;
Tanaka, Toshikatsu .
ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (14) :1824-1831