Supramolecular isomerism of Cu(I) and 3,5-di-2-pyridyl-1,2,4-triazolate via in situ solvothermal ligand reaction: meso-helix and luminescence

被引：12

作者：

Cheng, Lin ^{[1
]}

Cao, Qingna ^{[1
]}

Zhang, Limin ^{[1
]}

Gou, Shaohua ^{[1
]}

机构：

[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 65卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Supramolecular isomerism; 3,5-Di-2-pyridyl-1,2,4-triazolate; Meso-helix; Luminescence; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; POROUS PROPERTY; BUILDING-BLOCK; FRAMEWORKS; CHAINS; COPPER(I); CONSTRUCTION; NETWORK; ZIGZAG;

D O I：

10.1080/00958972.2012.682306

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The sixth supramolecular isomer of Cu(I) and 3,5-di-2-pyridyl-1,2,4-triazolate (2-pytz), [Cu-2(2-pytz)(2)](n) (1), via in situ solvothermal ligand reaction, has been synthesized and characterized as a rare meso-helical chain. Complex 1 exhibits high thermal stability (until 400 degrees C) confirmed by thermogravimetric analysis and has potential applications as an optical material. This research makes the maximum number of genuine supramolecular isomers with structural characterization, found for coordination polymers, six.

引用

页码：1821 / 1828

页数：8