1:1 and 2:1 Copper(II) Adduct Complexes with a Tripodal Ligand and Imidazole, Pyridine, and 4,4′-Bipyridine

被引：3
作者：
Qi, Zhao-Peng [1 ]
Sun, Jin-Yu [1 ]
Xu, Han [1 ]
Hu, Feng-Kai [1 ]
Zhang, Hui [1 ]
Liu, Wei-Bing [1 ]
机构：
[1] Huangshan Univ, Dept Chem, Huangshan, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2011年 / 637卷 / 14-15期
基金：
中国国家自然科学基金;
关键词：
Copper; Crystal growth; Self-assembly; Tripodal ligands; Mass spectrometry; MERCURY(II) HALIDE-COMPLEXES; CARBON-DIOXIDE FIXATION; PI-PI STACKING; COORDINATION POLYMERS; ZINC(II) COMPLEXES; CRYSTAL; PH; ARCHITECTURES; EXCHANGE;
D O I：
10.1002/zaac.201100201
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Four new copper(II) complexes [Cu(HL)(im)](ClO4)2 (1), [Cu(HL)(py)](ClO4)2 (2), [Cu2(HL)2(bpy)2](ClO4)4 center dot H2O (3), and [Cu2(HL)2(bpy)](ClO4)4 center dot H2O (4) (im = imidazole; py = pyridine; bpy = 4,4'-bipyridine) were synthesized by reactions of tripodal ligandN1-(2-aminoethyl)-N1-(1H-imidazol-4-ylmethyl)-ethane-1,2-diamine(HL) and Cu(ClO4)2 center dot 6H2O with different nitrogen-containing aromatic ligands. It was found that the size of the N-containing aromatic ligand, and the ratio of the ligand and metal ion, have great influence on the formation and structure of the complexes.
引用
收藏
页码：2288 / 2293
页数：6
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