Carbonaceous deposits on alumina as catalysts and supports

被引：10

作者：

Fiedorow, R ^{[1
]}

Franski, R ^{[1
]}

Krawczyk, A ^{[1
]}

Beszterda, S ^{[1
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, Poznan, Poland

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2004年 / 65卷 / 2-3期

关键词：

chemical synthesis;

D O I：

10.1016/j.jpcs.2003.08.042

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Studies of carbonaceous deposits, intercalated within alumina pores, were carried out from the point of view of their catalytic activity for a number of reactions of alkyl-substituted benzenes. Alumina was not active for ammoxidation of ethylbenzene and m-xylene as well as oxidative dehydrogenation of ethylbenzene until certain amount of the deposit was generated on acid sites of alumina surface. Carbonaceous deposits formed during reactions of decomposition of 2-propanol and hexafluoro-2-propanol were used as supports for platinum catalysts for hydrosilylation of allyl chloride and 1-octene to result in excellent selectivity. Precursor of carbonaceous deposit formed from hexafluoro-2-propanol has been identified and scheme of the deposit formation was proposed. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：627 / 632

页数：6

共 13 条

[1] AAMIEC J, 2002, 13 INT S ORG CHEM 35, P132
[2] FIEDOROW R, 1990, STUD SURF SCI CATAL, V55, P853
[3] Guisnet M., 1997, HDB HETEROGENEOUS CA, V2, P626
[4] Henriques CA, 1997, STUD SURF SCI CATAL, V105, P933
[5] HUDLICKY M, 1992, CHEM ORGANIC FLUORIN, P572
[6] On the topography and morphology of carbon deposits prepared by pyrolysis of alcohols on the surface of silica gel
Leboda, R
Charmas, B
Marciniak, M
Skubiszewska-Zieba, J
[J]. MATERIALS CHEMISTRY AND PHYSICS, 1999, 58 (02) : 146 - 155
[7] Likholobov VA, 2001, NATO SCI SER II MATH, V13, P295
[8] CARBONACEOUS DEPOSITS AS CATALYSTS FOR OXYDEHYDROGENATION OF ALKYLBENZENES
LISOVSKII, AE
AHARONI, C
[J]. CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1994, 36 (01): : 25 - 74
[9] MARCINIEC B, 2002, SILICON CHEM, V1, P155, DOI DOI 10.1023/A:1021235922742
[10] MARCINIEC B, 1992, COMPREHENSIVE HDB HY, P29

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