Synthesis and characterization of tris(2-pyridylthio)methanido Zn complex with a Zn-C bond and DFT calculation of its one-electron oxidized species

被引：22

作者：

Kitano, Ken'ichi ^{[1
]}

Kuwamura, Naoto ^{[1
]}

Tanaka, Rika ^{[1
]}

Santo, Ryoko ^{[1
]}

Nishioka, Takanori ^{[1
]}

Ichimura, Akio ^{[1
]}

Kinoshita, Isamu ^{[1
]}

机构：

[1] Osaka City Univ, Dept Mat Sci & Chem, Sumiyoshi Ku, Osaka 5588585, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 11期

基金：

欧洲研究理事会; 欧盟地平线“2020”;

关键词：

D O I：

10.1039/b715996j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tris(2-pyridylthio)methane (tptmH) reacts with ZnCl(2) producing the Zn-C containing complex of [ZnCl(tptm)], whose cyclic voltammogram shows an irreversible oxidation peak at 0.2 V vs. E(0)'(Fc(+/0)). DFT calculations suggested that le(-) oxidation should occur at the tptm ligand resulting in the cleavage of the Zn-C bond, leading to decomposition of the complex.

引用

页码：1314 / 1316

页数：3

共 7 条

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[4] A METALLOTRICYCLE - SYNTHESIS, ONE-ELECTRON REDUCTION, AND CRYSTAL-STRUCTURE OF THE THERMALLY ROBUST COMPLEX TRIS-ORTHO-XYLIDENETUNGSTEN(VI), [W(CH2C6H4CH2-ORTHO)3]
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[5] Synthesis and characterization of the asymmetrically coordinated dinuclear complex [{L(Ph2acac)FeIII}(μ-O){FeIII(Cl4-cat)L}](ClO4) and its one-electron reduced and oxidized forms. Models for dinuclear non-heme active sites
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JBIC Journal of Biological Inorganic Chemistry, 1998, 3 : 96 - 106
[6] Synthesis and characterization of the asymmetrically coordinated dinuclear complex [{L(Ph2acac)FeIII}(μ-O){FeIII(Cl4-cat)L}](ClO4) and its one-electron reduced and oxidized forms.: Models for dinuclear non-heme active sites
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JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 1998, 3 (01): : 96 - 106
[7] ORGANOMETALLIC CHALCOGEN COMPLEXES .20. STEREOCHEMICAL CHARACTERIZATION OF AN OXIDIZED IRON-SULFUR DIMER, FE(H5-C5H5)(CO)(SCH3)!2+ - A PARAMAGNETIC CATION EFFECTIVELY CONTAINING A ONE-ELECTRON METAL-METAL BOND
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (25) : 7472 - &

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