Synthesis and characterization of Cp3Ru3B3H8, Cp = η5-C5Me5, exhibiting a capped nido geometry.: Cluster geometry driven by hydrogen bridging

被引：27

作者：

Lei, XJ ^{[1
]}

Shang, MY ^{[1
]}

Fehlner, TP ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 16期

关键词：

D O I：

10.1021/ic980470i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new ruthenaborane, CP*3RU3B3H8, possesses a capped, five atom nido-cluster geometry rather than the more common octahedral geometry observed previously for seven skeletal electron pair M3B3 clusters. Comparison with the known, isoelectronic closo-1,2,3-{Cp*Co}(3)B3H5 shows that a more open capped geometry is favored as the number of endo-hydrogen atoms associated with the cluster framework increases.

引用

页码：3900 / 3901

页数：2

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Synthesis and characterization of Cp3*Ru3B3H8, Cp* = η5-C5Me5, exhibiting a capped nido geometry.: Cluster geometry driven by hydrogen bridging

Synthesis and characterization of Cp3Ru3B3H8, Cp = η5-C5Me5, exhibiting a capped nido geometry.: Cluster geometry driven by hydrogen bridging