Synthesis of novel palladium OCN-pincer complexes:: unprecedented sequential C(sp3)-H activation and aerobic oxidation in the reaction of N,N-dialkyl-3-[(N,N-dimethylamino)methyl]-2-iodoanilines with Pd2(dba)3

被引：16

作者：

Solé, D

Vallverdú, L

Solans, X

Font-Bardia, M

机构：

[1] Univ Barcelona, Fac Farm, Lab Quim Organ, E-08028 Barcelona, Spain

[2] Univ Barcelona, Dept Cristallog Mineral & Diposits Minerals, E-08028 Barcelona, Spain

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 21期

关键词：

D O I：

10.1039/b502854j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of N,N-dialkyl-3-[(N,N-dimethylamino)methyl]-2-iodoanilines with Pd-2(dba)(3) under O-2 gives palladium OCN-pincer complexes by means of an unprecedented process that involves the formal aerobic oxidation of C(sp(3))-H bonds at the a position of the aniline N atom.

引用

收藏

页码：2738 / 2740

页数：3

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