Influence of silver doping on the phase transformation and crystallite growth of electrospun TiO2 nanofibers

被引:32
作者
Park, Ju-Young [1 ,2 ]
Yun, Je-Jung [3 ]
Hwang, Cheol-Ho
Lee, In-Hwa [1 ]
机构
[1] Chosun Univ, Dept Environm Engn, Team Biohydrogen Prod BK21, Kwangju 501759, South Korea
[2] Seoul Natl Univ, Dept Phys & Astron, Seoul 151747, South Korea
[3] Nano Bio Res Ctr, Nam Myeon Jangseong Gun 515893, Jeollanam Do, South Korea
关键词
Nanomaterials; Electrospun; TiO2; Nanofibers; Ag doping; Phase transformation; PHOTOCATALYTIC ACTIVITY; FABRICATION; FIBERS; RUTILE;
D O I
10.1016/j.matlet.2010.09.008
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ag doped TiO2 nanofibers were fabricated by electrospinning technique using polyvinyl pyrrolidone (PVP) and titanium isopropoxide (TiP) as precursor. The effects of silver and calcination temperature on the preparation of electrospun TiO2 nanofibers were investigated. The calcination temperature determines the TiO2 phases as ether anatase or rutile. When the calcination temperature increased, crystallite size of TiO2 nanofiber increased. The crystallite size of Ag doped TiO2 nanofiber is smaller than that of the pure TiO2 nanofiber because silver is retrained in this phase transformation. Silver controlled the phase transformation as well as had an inhibition effect on the growth of anatase crystallite. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:2692 / 2695
页数:4
相关论文
共 19 条
[1]   Photocatalytic activity of titania fibers obtained by electrospinning [J].
Alves, A. K. ;
Berutti, F. A. ;
Clemens, F. J. ;
Graule, T. ;
Bergmann, C. P. .
MATERIALS RESEARCH BULLETIN, 2009, 44 (02) :312-317
[2]   ANATASE CRYSTAL-GROWTH AND PHASE-TRANSFORMATION TO RUTILE IN HIGH-AREA TIO2, MOO3-TIO2 AND OTHER TIO2-SUPPORTED OXIDE CATALYTIC-SYSTEMS [J].
AMORES, JMG ;
ESCRIBANO, VS ;
BUSCA, G .
JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (08) :1245-1249
[3]   SOLID-STATE AND SURFACE-CHEMISTRY OF CUO-TIO2 (ANATASE) POWDERS [J].
AMORES, JMG ;
ESCRIBANO, VS ;
BUSCA, G ;
LORENZELLI, V .
JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (06) :965-971
[4]   Spectroscopic investigation of the composition of electrospun titania nanofibers [J].
Bender, E. T. ;
Katta, P. ;
Chase, G. G. ;
Ramsier, R. D. .
SURFACE AND INTERFACE ANALYSIS, 2006, 38 (09) :1252-1256
[5]   Effect of silver doping on the phase transformation and grain growth of sol-gel titania powder [J].
Chao, HE ;
Yun, YU ;
Xingfang, HU ;
Larbot, A .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2003, 23 (09) :1457-1464
[6]  
Cullity BD, 2001, Elements of X-ray Diffraction
[7]   Titanium dioxide nanoribers prepared by using electrospinning method [J].
Ding, B ;
Kim, CK ;
Kim, HY ;
Se, MK ;
Park, SJ .
FIBERS AND POLYMERS, 2004, 5 (02) :105-109
[8]   Morphology and crystalline phase study of electrospun TiO2-SiO2 nanofibres [J].
Ding, B ;
Kim, H ;
Kim, C ;
Khil, M ;
Park, S .
NANOTECHNOLOGY, 2003, 14 (05) :532-537
[9]   A study on the electron transport properties of TiO2 electrodes in dye-sensitized solar cells [J].
Lee, Kun-Mu ;
Suryanarayanan, Vembu ;
Ho, Kuo-Chuan .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2007, 91 (15-16) :1416-1420
[10]   Fabrication of titania nanofibers by electrospinning [J].
Li, D ;
Xia, YN .
NANO LETTERS, 2003, 3 (04) :555-560