The use of carboranylphosphite ligands in Rh-catalyzed hydroformylation of alkenes in supercritical carbon dioxide

被引：1

作者：

Lyubimov, S. E. ^{[1
]}

Petrovskii, P. V. ^{[1
]}

Rastorguev, E. A. ^{[1
]}

Verbitskaya, T. A. ^{[1
]}

Kalinin, V. N. ^{[1
]}

Davankov, V. A. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2011年 / 60卷 / 10期

关键词：

carboranylphosphites; hydroformylation; supercritical carbon dioxide; rhodium; PHOSPHORUS-CONTAINING HETEROCYCLES; ASYMMETRIC HYDROGENATION; PHOSPHITES; CARBORANES; ALDEHYDES; RING;

D O I：

10.1007/s11172-011-0316-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel carborane-containing phosphites were synthesized. The efficiency of the ligands was tested in the Rh-catalyzed hydroformylation of styrene, hept-1-ene, and oct-1-ene in super-critical carbon dioxide (scCO(2)) and toluene. The use of scCO(2) as the reaction medium allows one to attain higher conversions and regioselectivities compared to toluene.

引用

页码：2074 / 2077

页数：4

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