WO3 nanorods/graphene nanocomposites for high-efficiency visible-light-driven photocatalysis and NO2 gas sensing

被引:488
|
作者
An, Xiaoqiang [1 ,2 ]
Yu, Jimmy C. [1 ,2 ]
Wang, Yu [3 ,4 ]
Hu, Yongming [3 ,4 ]
Yu, Xuelian [5 ]
Zhang, Guangjin [5 ]
机构
[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
[2] Chinese Univ Hong Kong, Inst Environm Energy & Sustainabil, Shatin, Hong Kong, Peoples R China
[3] Hong Kong Polytech Univ, Dept Appl Phys, Hong Kong, Hong Kong, Peoples R China
[4] Hong Kong Polytech Univ, Mat Res Ctr, Hong Kong, Hong Kong, Peoples R China
[5] Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
基金
美国国家科学基金会;
关键词
REDUCED GRAPHENE OXIDE; TUNGSTEN-OXIDE; ELECTROCHROMIC PROPERTIES; HYDROGEN-PRODUCTION; CARBON NANOTUBES; NANORODS; COMPOSITES; FILMS; NANOSTRUCTURES; NANOPARTICLES;
D O I
10.1039/c2jm16709c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
One-dimensional (1-D) nanostructures are of great importance due to their superior charge transport properties. Anchoring 1-D semiconductor nanomaterials on graphene offers potential advantages in photoelectrochemical and sensing applications. This paper presents a systematic investigation on the incorporation of WO3 nanorods and graphene for high-efficiency visible-light-driven photocatalysis and NO2 gas sensing. This novel composite shows remarkably enhanced performance compared to pure WO3 nanorods for these applications. The high photocatalytic activity of the WO3/graphene nanocomposite is found to be related to the increased adsorption toward chemical species, enhanced light absorption and efficient charge separation and transfer. Meanwhile, the improved conductivity, specific electron transfer and increased gas adsorption also contribute to their superior sensitivity and selectivity to NO2 gas.
引用
收藏
页码:8525 / 8531
页数:7
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