WO3 nanorods/graphene nanocomposites for high-efficiency visible-light-driven photocatalysis and NO2 gas sensing

被引:489
|
作者
An, Xiaoqiang [1 ,2 ]
Yu, Jimmy C. [1 ,2 ]
Wang, Yu [3 ,4 ]
Hu, Yongming [3 ,4 ]
Yu, Xuelian [5 ]
Zhang, Guangjin [5 ]
机构
[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
[2] Chinese Univ Hong Kong, Inst Environm Energy & Sustainabil, Shatin, Hong Kong, Peoples R China
[3] Hong Kong Polytech Univ, Dept Appl Phys, Hong Kong, Hong Kong, Peoples R China
[4] Hong Kong Polytech Univ, Mat Res Ctr, Hong Kong, Hong Kong, Peoples R China
[5] Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
基金
美国国家科学基金会;
关键词
REDUCED GRAPHENE OXIDE; TUNGSTEN-OXIDE; ELECTROCHROMIC PROPERTIES; HYDROGEN-PRODUCTION; CARBON NANOTUBES; NANORODS; COMPOSITES; FILMS; NANOSTRUCTURES; NANOPARTICLES;
D O I
10.1039/c2jm16709c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
One-dimensional (1-D) nanostructures are of great importance due to their superior charge transport properties. Anchoring 1-D semiconductor nanomaterials on graphene offers potential advantages in photoelectrochemical and sensing applications. This paper presents a systematic investigation on the incorporation of WO3 nanorods and graphene for high-efficiency visible-light-driven photocatalysis and NO2 gas sensing. This novel composite shows remarkably enhanced performance compared to pure WO3 nanorods for these applications. The high photocatalytic activity of the WO3/graphene nanocomposite is found to be related to the increased adsorption toward chemical species, enhanced light absorption and efficient charge separation and transfer. Meanwhile, the improved conductivity, specific electron transfer and increased gas adsorption also contribute to their superior sensitivity and selectivity to NO2 gas.
引用
收藏
页码:8525 / 8531
页数:7
相关论文
共 50 条
  • [1] Synthesis of Graphene Oxide Interspersed in Hexagonal WO3 Nanorods for High-Efficiency Visible-Light Driven Photocatalysis and NH3 Gas Sensing
    Salama, Tarek M.
    Morsy, Mohamed
    Abou Shahba, Rabab M.
    Mohamed, Shimaa H.
    Mohamed, Mohamed Mokhtar
    FRONTIERS IN CHEMISTRY, 2019, 7
  • [2] Amelioration in the visible-light-driven photocatalysis by <002> faceted WO3 nanocuboids
    Qamar, M.
    Alhooshani, K.
    Ahmed, M. I.
    Azad, A-M.
    Merzougui, B.
    CATALYSIS COMMUNICATIONS, 2015, 70 : 21 - 25
  • [3] Growth mechanism and visible-light-driven photocatalysis of organic solvent dependent WO3 and nonstoichiometric WO3-x nanostructures
    Zhao, Linyan
    Xi, Xiaoli
    Liu, Yangsi
    Ma, Liwen
    Nie, Zuoren
    JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2020, 115 (339-347) : 339 - 347
  • [4] Enhanced NO2 gas sensing properties of WO3 nanorods encapsulated with ZnO
    An, Soyeon
    Park, Sunghoon
    Ko, Hyunsung
    Lee, Chongmu
    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2012, 108 (01): : 53 - 58
  • [5] Facile synthesis of WO3 micro/nanostructures by paper-assisted calcination for visible-light-driven photocatalysis
    Zhao, Linyan
    Xi, Xiaoli
    Liu, Yangsi
    Ma, Liwen
    Nie, Zuoren
    CHEMICAL PHYSICS, 2020, 528
  • [6] Faster response of NO2 sensing in graphene-WO3 nanocomposites
    Srivastava, Shubhda
    Jain, Kiran
    Singh, V. N.
    Singh, Sukhvir
    Vijayan, N.
    Dilawar, Nita
    Gupta, Govind
    Senguttuvan, T. D.
    NANOTECHNOLOGY, 2012, 23 (20)
  • [7] The reduced graphene oxide/WO3: Sensing properties for NO2 gas detection at room
    Fellah, M. Ferdi
    DIAMOND AND RELATED MATERIALS, 2021, 119
  • [8] Highly sensitive and rapidly responding room-temperature NO2 gas sensors based on WO3 nanorods/sulfonated graphene nanocomposites
    Wang, Tingting
    Hao, Juanyuan
    Zheng, Shengliang
    Sun, Quan
    Zhang, Di
    Wang, You
    NANO RESEARCH, 2018, 11 (02) : 791 - 803
  • [9] Visible-light-driven photocatalysis of heterostructure Ag/Bi2WO6 nanocomposites and their photocatalytic degradation of dye under visible light irradiation
    Dumrongrojthanath, Phattranit
    Phuruangrat, Anukorn
    Junploy, Patcharanan
    Thongtem, Somchai
    Thongtem, Titipun
    RESEARCH ON CHEMICAL INTERMEDIATES, 2016, 42 (03) : 1651 - 1662
  • [10] Synthesis of Fe-doped WO3 nanostructures with high visible-light-driven photocatalytic activities
    Song, Hui
    Li, Yaguang
    Lou, Zirui
    Xiao, Mu
    Hu, Liang
    Ye, Zhizhen
    Zhu, Liping
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2015, 166 : 112 - 120