Oxidation of 3-alkyl-substituted 2-pyrazolino[60]fullerenes:: A new formyl-containing building block for fullerene chemistry

被引：18

作者：

Delgado, Juan Luis ^{[2
,3
]}

Cardinali, Francois ^{[1
]}

Espildora, Eva ^{[2
,3
]}

Torres, M. Rosario

Langa, Fernando ^{[1
]}

Martin, Nazario ^{[2
,3
,4
]}

机构：

[1] Univ Castilla La Mancha, Inst Nanociencia Nanotecnol & Mat Mol, Toledo 45077, Spain

[2] Univ Complutense Madrid, Dept Quim Organ, E-28040 Madrid, Spain

[3] Univ Complutense Madrid, Lab Difracc Rayos X, Fac Ciencias Quim, E-28040 Madrid, Spain

[4] Fac Ciencias, IMDEA Nanociencia, Madrid, Spain

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 17期

关键词：

D O I：

10.1021/ol801308g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new building block for fullerene chemistry, endowed with a formyl group on C-3 of the 2-pyrazoline ring, has been prepared in a simple two-step synthesis by oxidation of readily available 3-alkyl-substituted 2-pyrazolino[60]fullerenes; the new building block paves the way for the preparation of new light-harvesting fullerenes.

引用

页码：3705 / 3708

页数：4

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