Mechanochemistry: opportunities for new and cleaner synthesis

被引：2389

作者：

James, Stuart L. ^{[1
]}

Adams, Christopher J. ^{[2
]}

Bolm, Carsten ^{[3
]}

Braga, Dario ^{[4
]}

Collier, Paul ^{[5
]}

Friscic, Tomislav ^{[6
]}

Grepioni, Fabrizia ^{[4
]}

Harris, Kenneth D. M. ^{[7
]}

Hyett, Geoff ^{[8
]}

Jones, William ^{[6
]}

Krebs, Anke ^{[3
]}

Mack, James ^{[9
]}

Maini, Lucia ^{[4
]}

Orpen, A. Guy ^{[2
]}

Parkin, Ivan P. ^{[10
]}

Shearouse, William C. ^{[9
]}

Steed, Jonathan W. ^{[11
]}

Waddell, Daniel C. ^{[9
]}

机构：

[1] Queens Univ Belfast, Sch Chem & Chem Engn, Belfast BT9 5AG, Antrim, North Ireland

[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[3] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany

[4] Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[5] Johnson Matthey Technol Ctr, Reading RG4 9NH, Berks, England

[6] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[7] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

[8] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

[9] Univ Cincinnati, Dept Chem, Cincinnati, OH 45221 USA

[10] UCL, Christopher Ingold Lab, Mat Res Ctr, London WC1H 0AJ, England

[11] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

POWDER DIFFRACTION DATA; SOLID-STATE SYNTHESIS; X-RAY-DIFFRACTION; CRYSTAL-STRUCTURE SOLUTION; METAL-ORGANIC FRAMEWORKS; SOLVENT-FREE SYNTHESIS; CROSS-COUPLING REACTIONS; DIRECT ALDOL REACTION; BALL-MILLING IRON; CENTER-DOT 2H(2)O;

D O I：

10.1039/c1cs15171a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aim of this critical review is to provide a broad but digestible overview of mechanochemical synthesis, i.e. reactions conducted by grinding solid reactants together with no or minimal solvent. Although mechanochemistry has historically been a sideline approach to synthesis it may soon move into the mainstream because it is increasingly apparent that it can be practical, and even advantageous, and because of the opportunities it provides for developing more sustainable methods. Concentrating on recent advances, this article covers industrial aspects, inorganic materials, organic synthesis, cocrystallisation, pharmaceutical aspects, metal complexes (including metal-organic frameworks), supramolecular aspects and characterization methods. The historical development, mechanistic aspects, limitations and opportunities are also discussed (314 references).

引用

页码：413 / 447

页数：35

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