M2Si5N8:Eu2+-based (M=Ca, Sr) red-emitting phosphors fabricated by nitrate reduction process

被引：24

作者：

Chen, Changcheng ^{[1
,2
]}

Chen, Wanjun ^{[1
]}

Rainwater, Benjamin ^{[2
]}

Liu, Lixin ^{[1
]}

Zhang, Hongliang ^{[1
]}

Liu, Yanxia ^{[1
]}

Guo, Xiaosong ^{[1
]}

Zhou, Jinyuan ^{[1
]}

Xie, Erqing ^{[1
]}

机构：

[1] Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Gansu, Peoples R China

[2] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA

来源：

OPTICAL MATERIALS | 2011年 / 33卷 / 11期

关键词：

M2Si5N8:Eu2+-based phosphors; Nitrate reduction; Photoluminescence; LED CONVERSION PHOSPHORS; LUMINESCENCE PROPERTIES; CRYSTAL-STRUCTURE; PHOTOLUMINESCENCE PROPERTIES; SILICON-NITRIDE; M2SI5N8EU2+ M; BA; CA; DIODE; NITRIDOSILICATE;

D O I：

10.1016/j.optmat.2011.04.014

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

M2Si5N8:Eu2+-based (M = Ca, Sr) red-emitting phosphors were fabricated at relatively low temperature (1200 degrees C) and atmospheric pressure using a simple solid-state reaction process. Several processing parameters were systematically investigated to optimize the phosphors structural characterization and photoluminescence performance, including the amount of europium and the properties of the precursor and activated materials. The as-prepared M2Si5N8:Eu2+-based (M = Ca, Sr) phosphors were orange in color and emitted intensively in the red region of 580-670 nm under 465 nm excitation. This simple fabrication technique can be readily used for the optimization of phosphor microstructures and high-performance red-emitting phosphors since it eliminates many air-sensitive precursors. (C). 2011 Elsevier B.V. All rights reserved.

引用

页码：1585 / 1590

页数：6

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