Improvement of impact-resistant property of glass fiber-reinforced composites by carbon nanotube-modified epoxy and pre-stretched fiber fabrics

Glass fiber-reinforced plastic composites (GFRPs) are often suffered to impact loadings; it is essential to improve its damage-resistant properties and understand the energy absorption mechanisms. In this work, the low-velocity impact behaviors of GFRPs were investigated in consideration of epoxy resins modified with 0, 0.4, and 0.75 % multi-walled carbon nanotubes (MWCNTs) by weight content and pre-stretched fabric at 0, 1.27, and 2.47 kg weight. In comparison with pure GFRPs sample, MWCNT-modified specimens are effective in improving the impact resistance under impact energies at 9, 16, and 22 J in terms of reduced damage factor and enhanced perforation threshold. Microscopic fractographic analysis indicated that the incorporation of MWCNTs in epoxy matrix offered additional mechanisms through breakage, bridging, and pull-out of carbon nanotubes to favor load transfer effect, prevent crack propagation, and thus dissipate more energy. The dynamic thermo-mechanical analysis proved that MWCNTs improved the storage modulus and glass transition temperature of the composites. In addition, the pre-stretched GFRP composites showed more impact resistant than the non-stretched ones through instant load transfer effect.