Janus-Like 3D Tectons: Self-Assembled 2D Arrays of Functional Units at a Defined Distance from the Substrate

被引：18

作者：

Bleger, David ^{[1
]}

Mathevet, Fabrice ^{[1
]}

Kreher, David ^{[1
]}

Attias, Andre-Jean ^{[1
]}

Bocheux, Amandine ^{[1
,2
]}

Latil, Sylvain ^{[2
]}

Douillard, Ludovic ^{[2
]}

Fiorini-Debuisschert, Celine ^{[2
]}

Charra, Fabrice ^{[2
]}

机构：

[1] Univ Paris 06, Lab Chim Polymeres, UMR 7610, 4 Pl Jussieu,Case 185, F-75252 Paris 05, France

[2] CEA, IRAMIS, Serv Phys & Chim Surfaces & Interfaces, Lab Organ Elect & Nanophoton, F-91191 Gif Sur Yvette, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 29期

关键词：

chirality; chromophores; scanning probe microscopy; self-assembly; supramolecular chemistry; PI-PI-INTERACTION; SELECTIVE ADSORPTION; ORGANIC-MOLECULES; METAL-SURFACES; INTERFACES; COPOLYMERS; CHIRALITY; NETWORKS; DESIGN;

D O I：

10.1002/anie.201008212

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Janus faces: The Janus-like 3D tecton is a doubly functionalized molecular building block that consists of two different faces (see picture, gray: A and blue: B) linked by a rigid spacer. A is designed to act as a pedestal capable of guiding 2D self-assembly on the substrate, while B is a functional entity. This versatile approach allows for the creation of periodic arrays of functional units at a defined distance from the conductive substrate. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6562 / 6566

页数：5

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