Effect of mineralizer on the hydrothermal synthesis of Bi0.5Na0.5TiO3 lead-free piezoelectric crystals

被引:0
作者
Yang, Hui [1 ]
Yang, Gai [1 ]
Liu, Yun [2 ]
Wang, Chuang [3 ]
机构
[1] Shaanxi Univ Sci & Technol, Sch Life Sci & Engn, Xian 710021, Peoples R China
[2] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia
[3] Shaanxi Railway Inst, Dept Highway & Bridge, Weinan 714000, Peoples R China
来源
SOFT MAGNETIC MATERIALS | 2011年 / 298卷
关键词
Hydrothermal synthesis; Lead-free; Piezoelectric ceramic; Bismuth sodium titanate; DIELECTRIC-PROPERTIES; ELECTRICAL-PROPERTIES; CERAMICS; BEHAVIOR; TITANATE; SYSTEM;
D O I
10.4028/www.scientific.net/AMR.298.209
中图分类号
TB33 [复合材料];
学科分类号
摘要
The effect of mineralizer upon the fabrication of lead-free, piezoelectric Bi0.5Na0.5TiO3 (BNT) was investigated using a hydrothermal reaction technique. Results indicated that BNT crystals can be formed in a basic environment controlled by a NaOH mineralizer. The morphologies and sizes of the resultant particles are determined by the concentration of NaOH: a lower alkaline concentration leads to the particles with a spherical shape consisting of a number of small, intergrown BNT crystals while a higher NaOH concentration (e.g. > 12 mol/L) results in large, individual BNT cubes. Possible growth mechanisms of the BNT particles were discussed in conjunction with surface hydration, dehydration and free water content during the hydrothermal reaction.
引用
收藏
页码:209 / +
页数:3
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