Development of Robust Metal-Supported SOFCs and Stack Components in EU METSAPP Consortium

被引:18
作者
Sudireddy, B. R. [1 ]
Nielsen, J. [1 ]
Persson, A. H. [1 ]
Thyden, K. [1 ]
Brodersen, K. [1 ]
Ramousse, S. [1 ]
Neagu, D. [2 ]
Stefan, E. [2 ]
Irvine, J. T. S. [2 ]
Geisler, H. [3 ]
Weber, A. [3 ]
Reiss, G. [4 ,9 ]
Schauperl, R. [5 ]
Rechberger, J. [5 ]
Froitzheim, J. [6 ]
Sachitanand, R. [6 ]
Falk-Windisch, H. [6 ]
Svensson, J. E. [6 ]
Lundberg, M. W. [7 ]
Berger, R. [7 ]
Westlinder, J. [7 ]
Hornauer, S. [8 ]
Kiefer, T. [8 ]
机构
[1] Tech Univ Denmark, Dept Energy Convers & Storage, Frederiksborgvej 399, DK-4000 Roskilde, Denmark
[2] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[3] KIT, Inst Appl Mat IAM WET, D-76131 Karlsruhe, Germany
[4] ICE Stromungsforsch GmbH, Hauptpl 13, A-8700 Leoben, Austria
[5] AVL List GmbH, Hans List Pl 1, A-8020 Graz, Austria
[6] Chalmers, Dept Chem & Chem Engn, S-41296 Gothenburg, Sweden
[7] AB Sandvik Mat Technol, SFFY 4371, SE-81181 Sandviken, Sweden
[8] ElringKlinger AG, Max Eyth Stasse 2, D-72581 Dettingen Unter Teck, Germany
[9] MCL Forschung GmbH, Roseggerstr 12, A-8700 Leoben, Austria
关键词
Degradation; Electrochemistry; Energy Conversion; Fuel Cell Stacks; Metal-supported Solid Oxide Cells; Modeling; Nanostructured Protective Coatings; Strontium Titanate; OXIDE FUEL-CELLS; CERMET ANODE; COATED INTERCONNECTS; NUMERICAL EVALUATION; BARRIER LAYERS; IMPEDANCE; OXIDATION; PERFORMANCE; DECONVOLUTION; EVAPORATION;
D O I
10.1002/fuce.201600191
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The potential of MS-SOFCs was demonstrated through the previous EU METSOFC project, which concluded that the development of oxidation resistant novel metal-supported solid oxide fule cell (MS-SOFC) design and stack is the requirement to advance this technology to the next level. The following EU METSAPP project has been executed with an overall aim of developing advanced metal-supported cells and stacks based on a robust, reliable and up-scalable technology. During the project, oxidation resistant nanostructured anodes based on modified SrTiO3 were developed and integrated into MS-SOFCs to enhance their robustness. In addition, the manufacturing of metal-supported cells with different geometries, scalability of the manufacturing process was demonstrated and more than 200 cells with an area of approximate to 150 cm(2) were produced. The electrochemical performance of different cell generations was evaluated and best performance and stability combination was observed with doped SrTiO3 based anode designs. Furthermore, numerical models to understand the corrosion behavior of the MS-SOFCs were developed and validated. Finally, the cost effective concept of coated metal interconnects was developed, which resulted in 90% reduction in Cr evaporation, three times lower Cr2O3 scale thickness and increased lifetime. The possibility of assembling these cells into two radically different stack designs was demonstrated.
引用
收藏
页码:508 / 516
页数:9
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