FTIR spectra and mechanical strength analysis of some selected rubber derivatives

被引:150
作者
Gunasekaran, S.
Natarajan, R. K.
Kala, A. [1 ]
机构
[1] Presidency Coll, PG & Res Dept Phys, Madras 600005, Tamil Nadu, India
[2] Pachaiyappas Coll, PG & Res Dept Phys, Madras 600030, Tamil Nadu, India
关键词
rubber materials; vulcanizates; reinforced materials; polyblends of NR with NBR and with EPDM; FTIR spectra; mechanical strength; tensile measurement and hardness;
D O I
10.1016/j.saa.2006.11.039
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Rubber materials have wide range of commercial applications such as, infant diapers, famine hygiene products, drug delivery devices and incontinency products such as rubber tubes, lyres, etc. In the present work, studies on mechanical properties of some selected rubber materials viz., natural rubber (NR), styrene butadiene rubber (SBR), nitrile butadiene rubber (NBR) and ethylene propylene diene monomer (EPDM) have been carried out in three states viz., raw, vulcanized and reinforced. To enhance the quality of rubber elastomers, an attempt is made to prepare new elastomers called polyblends. In the present study an attempt is made to blend NR with NBR and with EPDM. We here report, a novel approach for the evaluation of various physico-mechanical properties such as mechanical strength, tensile strength, elongation and hardness. The method is simple, direct and fast and involves infrared spectral measurements for the evaluation of these properties. With the applications of modern infrared spectroscopy, the mechanical strength of these rubber materials have been analyzed by calculating the internal standards among the methyl and methylene group vibrational frequencies obtained from FTIR spectroscopy. Also the tensile strength measurements carried out by universal testing machine. The results pertaining physico-mechanical properties of the rubber derivatives undertaken in the present study obtained by IR-based method are in good agreement with data resulted from the standard methods. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:323 / 330
页数:8
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