Polyvinylbutyral assisted synthesis and characterization of kesterite quaternary semiconductor Cu2ZnSnSe4 nanofibers by electrospinning route

被引：10
作者：
Lee, Chia-Rong
Chen, Lin-Jer [1 ]
机构：
[1] Natl Cheng Kung Univ, Dept Photon, Tainan 701, Taiwan
来源：
SOLAR ENERGY MATERIALS AND SOLAR CELLS | 2016年 / 151卷
关键词：
Electrospinning; Nanofibers; Kesterite; Optical properties; FILM SOLAR-CELLS; THIN-FILM; SOLID-SOLUTIONS; POLYMER; NANOPARTICLES; SELENIZATION; NANOCRYSTALS; FABRICATION; DIFFUSION; ABSORBER;
D O I：
10.1016/j.solmat.2016.02.019
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Kesterite quaternary semiconductor Cu2ZnSnSe4 nanocrystals were successfully prepared via a relatively simple electrospinning route and characterized using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and transmission electron microscopy (TEM). Semiconductor Cu2ZnSnSe4 nanofibers were obtained for PVB/ Cu2ZnSnSe4 precursor at an applied voltage of 20 kV after annealing treatment at 500 degrees C for 2 h. The optical property of Cu2ZnSnSe4 nano crystals was also recorded by means of UV-vis absorption spectroscopy. It was shown that the dimension effect of composites could be enhanced by increasing the electrospinning conditions (voltage, distances, concentrations, viscosity) and the CZTSe nanofibers prepared at annealing process exhibited more intense optical properties. Temperature dependent studies were conducted and the annealing of composites was found to be the key factor in determining the phase formation. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码：24 / 29
页数：6
相关论文
共 43 条
[1]   A High Efficiency Electrodeposited Cu2ZnSnS4 Solar Cell [J].
Ahmed, Shafaat ;
Reuter, Kathleen B. ;
Gunawan, Oki ;
Guo, Lian ;
Romankiw, Lubomyr T. ;
Deligianni, Hariklia .
ADVANCED ENERGY MATERIALS, 2012, 2 (02) :253-259
[2]   Cu2Zn1-xCdxSn(Se1-ySy)4 solid solutions as absorber materials for solar cells [J].
Altosaar, M. ;
Raudoja, J. ;
Timmo, K. ;
Danilson, M. ;
Grossberg, M. ;
Krustok, J. ;
Mellikov, E. .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2008, 205 (01) :167-170
[3]   Correlation between physical, electrical, and optical properties of Cu2ZnSnSe4 based solar cells [J].
Brammertz, G. ;
Buffiere, M. ;
Mevel, Y. ;
Ren, Y. ;
Zaghi, A. E. ;
Lenaers, N. ;
Mols, Y. ;
Koeble, C. ;
Vleugels, J. ;
Meuris, M. ;
Poortmans, J. .
APPLIED PHYSICS LETTERS, 2013, 102 (01)
[4]   Electrospinning predictions using artificial neural networks [J].
Brooks, Hadley ;
Tucker, Nick .
POLYMER, 2015, 58 :22-29
[5]   Compositionally controlled band gap and photoluminescence of ZnSSe nanofibers by electrospinning [J].
Chen, Lin-Jer ;
Lee, Chia-Rong ;
Chuang, Yu-Ju ;
Wu, Zhao-Han ;
Chen, Chienyi .
CRYSTENGCOMM, 2015, 17 (24) :4434-4438
[6]   Surface passivation assisted lasing emission in the quantum dots doped cholesteric liquid crystal resonating cavity with polymer template [J].
Chen, Lin-Jer ;
Lee, Chia-Rong ;
Chu, Chung-Liang .
RSC ADVANCES, 2014, 4 (95) :52804-52807
[7]   Directly electrospinning growth of single crystal Cu2ZnSnS4 nanowires film for high performance thin film solar cell [J].
Chen, Lin-Jer ;
Chuang, Yu-Ju .
JOURNAL OF POWER SOURCES, 2013, 241 :259-265
[8]   Diethylenetriamine assisted synthesis and characterization of stannite quaternary semiconductor Cu2ZnSnSe4 nanorods by self-assembly [J].
Chen, Lin-Jer ;
Chuang, Yu-Ju .
JOURNAL OF CRYSTAL GROWTH, 2013, 376 :11-16
[9]   Quaternary semiconductor derived and formation mechanism by non-vacuum route from solvothermal nanostructures for high-performance application [J].
Chen, Lin-Jer ;
Chuang, Yu-Ju .
MATERIALS LETTERS, 2013, 91 :372-375
[10]   Synthesis and Characterization of Cu(InxB1-x)Se2 Nanocrystals for Low-Cost Thin Film Photovoltaics [J].
Chen, Lin-Jer ;
Liao, Jiunn-Der ;
Chuang, Yu-Ju ;
Fu, Yaw-Shyan .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (11) :3704-3707
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