[FeIILSCoIIILS]2 ⇆ [FeIIILSCoIIHS]2 photoinduced conversion in a cyanide-bridged heterobimetallic molecular square

被引：110

作者：

Mercurol, Julie ^{[1
]}

Li, Yanling ^{[1
]}

Pardo, Emilio ^{[1
]}

Risset, Olivia ^{[1
]}

Seuleiman, Mannan ^{[1
]}

Rousseliere, Helene ^{[1
]}

Lescouezec, Rodrigue ^{[1
]}

Julve, Miguel ^{[2
]}

机构：

[1] Univ Paris 06, Inst Parisien Chim Mol, UMR 7201, F-75252 Paris, France

[2] Univ Valencia, Dept Quim Inorgan, ICMOL, Valencia 46980, Spain

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 47期

关键词：

INDUCED SPIN TRANSITION; ELECTRON-TRANSFER; BUILDING-BLOCKS; COMPLEX; CHAINS; MAGNETIZATION; TEMPERATURE;

D O I：

10.1039/c0cc02024a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The self-assembly of [Fe-III{B(pz)(4)}(CN)(3)](-) and [Co-II(bik)(2)(S)(2)](2+) affords the diamagnetic cyanide-bridged [(FeLSCoLSIII)-Co-II](2) molecular square which is converted into the corresponding magnetic [(FeLSCoHSII)-Co-III](2) species under light irradiation at relatively low temperatures.

引用

页码：8995 / 8997

页数：3

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