Reactivity of InCp* towards transition metal carbonyl clusters:: Synthesis and structural characterization of the Rh6(CO)16-x(InCP*)x mixed-metal cluster compounds, x=1-2

被引：6
作者：
Grachova, Elena V.
Linti, Gerald
机构：
[1] St Petersburg State Univ, Dept Chem, St Petersburg 198504, Russia
[2] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 22期
关键词：
rhodium; indium; cluster compounds;
D O I：
10.1002/ejic.200700198
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
With [Rh-6(CO)15(InCp*)], the first example of a transition metal carbonyl cluster with a coordinated InCp* (Cp* = C5Me5) fragment in the ligand environment is reported. This cluster with direct Rh-ln bonds forms in the reaction of the hexanuclear carbonyl rhodium cluster Rh-6(CO)(15)(NCMe) with InCp* under mild conditions. This is characterized by means of IR and NNIR spectroscopy and crystal structure analysis. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).
引用
收藏
页码：3561 / 3564
页数：4
相关论文
共 16 条
[1]   (PENTAMETHYLCYCLOPENTADIENYL)INDIUM(I) AND (PENTAMETHYLCYCLOPENTADIENYL)INDIUM(III) COMPOUNDS - SYNTHESES, REACTIVITIES, AND X-RAY-DIFFRACTION AND ELECTRON-DIFFRACTION STUDIES OF IN(C5ME5) [J].
BEACHLEY, OT ;
BLOM, R ;
CHURCHILL, MR ;
FAEGRI, K ;
FETTINGER, JC ;
PAZIK, JC ;
VICTORIANO, L .
ORGANOMETALLICS, 1989, 8 (02) :346-356
[2]   Insertion reactions of GaCp*, InCp* and In[C(SiMe3)3] into the Ru-Cl bonds of [(p-cymene)RuIICl2]2 and [Cp*RuIICl]4 [J].
Cokoja, M ;
Gemel, C ;
Steinke, T ;
Schröder, F ;
Fischer, RA .
DALTON TRANSACTIONS, 2005, (01) :44-54
[3]   Ligand effects on the structures of Rh6(CO)15L clusters [J].
Farrar, DH ;
Grachova, EV ;
Lough, A ;
Patirana, C ;
Poe, AJ ;
Tunik, SP .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (13) :2015-2019
[4]   The nature of the bonding in transition-metal compounds [J].
Frenking, G ;
Fröhlich, N .
CHEMICAL REVIEWS, 2000, 100 (02) :717-774
[5]   Transition metal chemistry of low valent group 13 organyls [J].
Gemel, C ;
Steinke, T ;
Cokoja, M ;
Kempter, A ;
Fischer, RA .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2004, (21) :4161-4176
[6]   Reactions of GaCp* with a hemilabile derivative of Rh6(CO)16 -: Synthesis and structural characterization of two novel heterometallic clusters:: Rh6(CO)13- (μ,κ3-Ph2PC2H3)(μ3-GaCp*) and Rh6(CO)13(κ1-Ph2PC2H3)(μ3-GaCp*)2 [J].
Grachova, Elena V. ;
Linti, Gerald ;
Stammler, Hans-Georg ;
Neumann, Beate ;
Tunik, Sergey P. ;
Wadepohl, Hubert .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 1 (01) :140-146
[7]   Novel rhodium and ruthenium carbonyl cluster complexes with face- and edge-bridging GaCp* ligands.: Synthesis and structural characterization of the Rh6(CO)12(μ3-GaCp*)4 and Ru6(η6-C)(μ2-CO)(CO) 13(μ3-GaCp*)2(μ2-GaCp*) clusters [J].
Grachova, EV ;
Jutzi, P ;
Neumann, B ;
Stammler, HG .
DALTON TRANSACTIONS, 2005, (22) :3614-3616
[8]   Unusual selective substitution of triply bridging carbonyl ligands for GaCp* in Rh6(CO)16.: Synthesis and structural characterization of the Rh6(μ3-CO)4-x(μ3-GaCp*)x(CO)12 clusters, x=1-4 [J].
Grachova, EV ;
Jutzi, P ;
Neumann, B ;
Schebaum, LO ;
Stammler, HG ;
Tunik, SP .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (03) :302-304
[9]   Pentamethylcyclopentadienylindium (Cp*In) as terminal ligand in the chemistry of chromium [J].
Jutzi, P ;
Neumann, B ;
Reumann, G ;
Schebaum, LO ;
Stammler, HG .
ORGANOMETALLICS, 1999, 18 (13) :2550-2552
[10]   Low valent aluminum and gallium compounds -: structural variety and coordination modes to transition metal fragments [J].
Linti, G ;
Schnöckel, H .
COORDINATION CHEMISTRY REVIEWS, 2000, 206 :285-319
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