Specific Heat Capacity of Nitrobenzene-Tetradecane Near the Liquid-Liquid Critical Point

被引：4

作者：

Losada-Perez, P. ^{[1
,3
]}

Cordoyiannis, G. ^{[2
]}

Cerdeirina, C. A. ^{[3
]}

Glorieux, C. ^{[2
]}

Thoen, J. ^{[2
]}

机构：

[1] Katholieke Univ Leuven, Dep Fys Sterrenkunde, Lab Akoestiek Therm Fys ATF, B-3001 Louvain, Belgium

[2] Katholieke Univ Leuven, Dept Sterrenkunde Nat Kunde, Lab Akoestiek Therm Fys, B-3001 Louvain, Belgium

[3] Univ Vigo, Dept Fis Aplicada, Orense 32004, Spain

来源：

INTERNATIONAL JOURNAL OF THERMOPHYSICS | 2010年 / 31卷 / 4-5期

关键词：

Adiabatic scanning calorimetry; Binary mixtures; Correlation length; Critical behavior; Isobaric heat capacity; COEXISTENCE CURVES;

D O I：

10.1007/s10765-010-0707-y

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

High-resolution adiabatic scanning calorimetry has been used to study the specific heat capacity anomaly of the nitrobenzene-tetradecane mixture near its upper critical point. The analysis, which is based on a method that uses heat capacity and enthalpy data, yields a value of the critical amplitude ratio A (+)/A (-) which is consistent with the universal, accepted one. The critical amplitude of the correlation length was derived via two-scale factor universality. All this information is compared to that reported in previous studies for nitrobenzene-alkane mixtures.

引用

页码：710 / 716

页数：7

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