Crystal structure of silver carbonate iodide Ag10(CO3)3I4

被引：1

作者：

Suzuki, Ryoji ^{[1
]}

Watanabe, Yuta ^{[1
]}

Yamane, Hisanori ^{[2
]}

Kitaura, Mamoru ^{[3
]}

Uchida, Kento ^{[1
]}

Matsushima, Yuta ^{[1
]}

机构：

[1] Yamagata Univ, Chem & Chem Engn, 4-3-16 Jonan, Yonezawa, Yamagata 9928510, Japan

[2] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, 2-1-1 Katahira, Sendai, Miyagi 9808577, Japan

[3] Yamagata Univ, Fac Sci, 1-4-12 Kojirakawa Machi, Yamagata 9908560, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2021年 / 77卷

关键词：

crystal structure; silver carbonate iodide; layered structure; HIGH IONIC-CONDUCTIVITY; SOLID ELECTROLYTES; X-RAY; STATE;

D O I：

10.1107/S2056989021006022

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title silver carbonate iodide, Ag-10(CO3)(3)I-4, decasilver(I) tris(carbonate) tetraiodide, was recently reported as a precursor of the new superionic conductor Ag-17(CO3)(3)I-11. Ag-10(CO3)(3)I-4, was prepared by heating a stoichiometric powder mixture of AgI and Ag2CO3 at 430 K. A single-crystal suitable for X-ray diffraction analysis was obtained by slow cooling of a melt with an AgI-rich composition down from 453 K. Ag-10(CO3)(3)I-4 exhibits a layered crystal structure packed along [10 (1) over bar], in which Ag atoms are intercalated between the layers of hexagonally close-packed I atoms, and CO3 groups. Up to now, Cs3Pb2(CO3)(3)I is the only other compound containing carbonate groups and iodide ions registered in the Inorganic Crystal Structure Database.

引用

页码：734 / +

页数：27

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